Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications

Masahito Murai; Hiroyuki Maekawa; Shino Hamao; Yoshihiro Kubozono; David Roy; Kazuhiko Takai

doi:10.1021/ol503723j

Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications

Masahito Murai, Hiroyuki Maekawa, Shino Hamao, Yoshihiro Kubozono, David Roy, Kazuhiko Takai

異分野基礎科学研究所

研究成果 › 査読

18 被引用数 (Scopus)

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Novel [6]phenacenes (fulminenes) with two long alkyl chains at the axis positions were synthesized. This short synthesis comprises the following three steps: (1) ruthenium-catalyzed direct C-H bond arylation; (2) conversion of directing groups by Wittig reaction; and (3) bismuth- or gold-catalyzed cyclization of vinyl ether. Organic field-effect transistor devices fabricated with a thin film of 3,11-di(tetradecyl)fulminene exhibited typical p-channel normally-off properties.

本文言語	English
ページ（範囲）	708-711
ページ数	4
ジャーナル	Organic Letters
巻	17
号	3
DOI	https://doi.org/10.1021/ol503723j
出版ステータス	Published - 2月 6 2015

ASJC Scopus subject areas

生化学
物理化学および理論化学
有機化学

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title = "Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications",

abstract = "Novel [6]phenacenes (fulminenes) with two long alkyl chains at the axis positions were synthesized. This short synthesis comprises the following three steps: (1) ruthenium-catalyzed direct C-H bond arylation; (2) conversion of directing groups by Wittig reaction; and (3) bismuth- or gold-catalyzed cyclization of vinyl ether. Organic field-effect transistor devices fabricated with a thin film of 3,11-di(tetradecyl)fulminene exhibited typical p-channel normally-off properties.",

author = "Masahito Murai and Hiroyuki Maekawa and Shino Hamao and Yoshihiro Kubozono and David Roy and Kazuhiko Takai",

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T1 - Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications

AU - Murai, Masahito

AU - Maekawa, Hiroyuki

AU - Hamao, Shino

AU - Kubozono, Yoshihiro

AU - Roy, David

AU - Takai, Kazuhiko

PY - 2015/2/6

Y1 - 2015/2/6

N2 - Novel [6]phenacenes (fulminenes) with two long alkyl chains at the axis positions were synthesized. This short synthesis comprises the following three steps: (1) ruthenium-catalyzed direct C-H bond arylation; (2) conversion of directing groups by Wittig reaction; and (3) bismuth- or gold-catalyzed cyclization of vinyl ether. Organic field-effect transistor devices fabricated with a thin film of 3,11-di(tetradecyl)fulminene exhibited typical p-channel normally-off properties.

AB - Novel [6]phenacenes (fulminenes) with two long alkyl chains at the axis positions were synthesized. This short synthesis comprises the following three steps: (1) ruthenium-catalyzed direct C-H bond arylation; (2) conversion of directing groups by Wittig reaction; and (3) bismuth- or gold-catalyzed cyclization of vinyl ether. Organic field-effect transistor devices fabricated with a thin film of 3,11-di(tetradecyl)fulminene exhibited typical p-channel normally-off properties.

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Transition-metal-catalyzed facile access to 3,11-dialkylfulminenes for transistor applications

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