@article{758012e85aa4471aa536ee923e230131,
title = "TMSCl as a mild and effective source of acidic catalysis in fischer glycosidation and use of propargyl glycoside for anomeric protection",
abstract = "Practical Fischer glycosidation was effected at room temperature or 60°C by using 5 to 10 equiv. of TMSCl. The anomeric propargyl group formed by this method was found to be a versatile new protecting group, being stable in neat TFA but readily cleaved by treatment with Co2(CO)8 and TFA in CH2Cl2via the formation of an alkyne–Co complex.",
keywords = "Acid catalyst, Fischer glycosidation, Protective group, TMSCl",
author = "Minoru Izumi and Koichi Fukase and Shoichi Kusumoto",
note = "Funding Information: The present work was ˆnancially supported in part by ``Research for the Future'' program No. 97L00502 from the Japan Society for the Promotion of Science, by special coordination funds from the Science and Technology Agency of the Japanese Government, and by grant-aid for scientiˆc research Nos. 09044086 and 12640571 from the Ministry of Education, Science and Culture, Japan.",
year = "2002",
doi = "10.1271/bbb.66.211",
language = "English",
volume = "66",
pages = "211--214",
journal = "Bioscience, Biotechnology and Biochemistry",
issn = "0916-8451",
publisher = "Japan Society for Bioscience Biotechnology and Agrochemistry",
number = "1",
}