Synthesis of 5-deoxy-5-hydroxyphosphinyl-d-mannopyranoses

Tadashi Hanaya, Kunihiro Hirose, Hiroshi Yamamoto

    研究成果査読

    8 被引用数 (Scopus)

    抄録

    The title sugar analogues (13) were synthesized by starting with known methyl (E)-5,6-dideoxy-2,3-O-isopropylidene-6-nitro-α-d-lyxo-hex-5-enofuranoside (5a) in six steps through the key intermediate, methyl 5-deoxy-5-dimethoxy-phosphinyl-2,3-O-isopropylidene-α-d-mannofuranoside 8a). The products (13) were converted into the corresponding penta-O-acetyl-5-methoxyphosphinyl derivatives (14), whose structures and conformations (mostly 4C1) were established by spectroscopy.

    本文言語English
    ページ(範囲)2557-2564
    ページ数8
    ジャーナルHeterocycles
    36
    11
    DOI
    出版ステータスPublished - 11月 1 1993

    ASJC Scopus subject areas

    • 分析化学
    • 薬理学
    • 有機化学

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