Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)2, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)2

Yasushi Nishihara; Hiroyuki Onodera; Kohtaro Osakada

doi:10.1039/b308741g

Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C₆F₅)I(PEt₃)₂

Yasushi Nishihara, Hiroyuki Onodera, Kohtaro Osakada

研究成果 › 査読

53 被引用数 (Scopus)

抄録

The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C₆F₅)I(PR₃)₂(PR₃=PEt₃, PMe₂Ph, PMePh₂) in the presence of Ag₂O afforded trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PR₃)₂ which are stabilized by fluorine atoms in the ortho positions.

本文言語	English
ページ（範囲）	192-193
ページ数	2
ジャーナル	Chemical Communications
巻	4
号	2
DOI	https://doi.org/10.1039/b308741g
出版ステータス	Published - 1月 1 2004
外部発表	はい

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/b308741g

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「Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C₆F₅)I(PEt₃)₂」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C₆F₅)(2,4,6-C₆F₃H₂)(PEt₃)₂, derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C₆F₅)I(PEt₃)₂. / Nishihara, Yasushi; Onodera, Hiroyuki; Osakada, Kohtaro.

In: Chemical Communications, Vol. 4, No. 2, 01.01.2004, p. 192-193.

研究成果 › 査読

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