Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

Kyosuke Satake; Isao Umemoto; Kunihiro Usumoto; Masaru Kimura; Shiro Morosawa; Tsutomu Kumagai; Toshio Mukai

doi:10.3987/COM-89-5231

Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

Kyosuke Satake, Isao Umemoto, Kunihiro Usumoto, Masaru Kimura, Shiro Morosawa, Tsutomu Kumagai, Toshio Mukai

研究成果 › 査読

2 被引用数 (Scopus)

抄録

[8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.

本文言語	English
ページ（範囲）	163-172
ページ数	10
ジャーナル	Heterocycles
巻	31
号	1
DOI	https://doi.org/10.3987/COM-89-5231
出版ステータス	Published - 1月 1 1990

ASJC Scopus subject areas

分析化学
薬理学
有機化学

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10.3987/COM-89-5231

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title = "Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes",

abstract = "[8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.",

author = "Kyosuke Satake and Isao Umemoto and Kunihiro Usumoto and Masaru Kimura and Shiro Morosawa and Tsutomu Kumagai and Toshio Mukai",

year = "1990",

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doi = "10.3987/COM-89-5231",

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T1 - Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

AU - Satake, Kyosuke

AU - Umemoto, Isao

AU - Usumoto, Kunihiro

AU - Kimura, Masaru

AU - Morosawa, Shiro

AU - Kumagai, Tsutomu

AU - Mukai, Toshio

PY - 1990/1/1

Y1 - 1990/1/1

N2 - [8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.

AB - [8](3,6)Azepinophane (methyl 3,6-octano-1H-azepine-1-carboxylate) and [8](3,6) oxepinophane (3,6-octanooxepin) were synthesized from bicyclo [8.2.2 ] undecadiene, and structural features of them were also studied on the basis of their spectral data. The effect of the substituents at 3 and 6 positions on the structure of 1H-azepine ring was elucidated by comparison of several 3,6-dialkyl-1H-azepine derivatives with the title azepinophane.

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Synthesis and characterization of [8] (3, 6) azepinophane and [8] (3,6) oxepinophanes

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