Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR

Yukihiro Yoshida; Yoshihiro Kubozono; Setsuo Kashino; Youichi Murakami

doi:10.1016/S0009-2614(98)00598-3

Structure and electronic properties of Cs₃C₆₀ under ambient pressure revealed by X-ray diffraction and ESR

Yukihiro Yoshida, Yoshihiro Kubozono, Setsuo Kashino, Youichi Murakami

異分野基礎科学研究所

研究成果 › 査読

14 被引用数 (Scopus)

抄録

The structure and electronic properties of Cs₃C₆₀ under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs₃C₆₀ takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs₃C₆₀ exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.

本文言語	English
ページ（範囲）	31-36
ページ数	6
ジャーナル	Chemical Physics Letters
巻	291
号	1-2
DOI	https://doi.org/10.1016/S0009-2614(98)00598-3
出版ステータス	Published - 7月 10 1998

ASJC Scopus subject areas

物理学および天文学（全般）
物理化学および理論化学

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10.1016/S0009-2614(98)00598-3

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引用スタイル

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title = "Structure and electronic properties of Cs3C60 under ambient pressure revealed by X-ray diffraction and ESR",

abstract = "The structure and electronic properties of Cs3C60 under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs3C60 takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs3C60 exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.",

author = "Yukihiro Yoshida and Yoshihiro Kubozono and Setsuo Kashino and Youichi Murakami",

note = "Funding Information: This work was financially supported by the Venture Business Laboratory of Okayama University. The authors are indebted to Professor Yoshihiro Iwasa and Mr. Susumu Taga of JAIST for the use of a Raman spectrometer and Professor Kokichi Oshima and Dr. Takashi Kambe of the Department of Physics, Okayama University, for valuable discussions on ESR. YY is grateful to Professor Gunzi Saito of Kyoto University for his valuable suggestion on the electronic structure in Cs 3 C 60 . Copyright: Copyright 2018 Elsevier B.V., All rights reserved.",

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AU - Kashino, Setsuo

AU - Murakami, Youichi

N1 - Funding Information: This work was financially supported by the Venture Business Laboratory of Okayama University. The authors are indebted to Professor Yoshihiro Iwasa and Mr. Susumu Taga of JAIST for the use of a Raman spectrometer and Professor Kokichi Oshima and Dr. Takashi Kambe of the Department of Physics, Okayama University, for valuable discussions on ESR. YY is grateful to Professor Gunzi Saito of Kyoto University for his valuable suggestion on the electronic structure in Cs 3 C 60 . Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

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N2 - The structure and electronic properties of Cs3C60 under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs3C60 takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs3C60 exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.

AB - The structure and electronic properties of Cs3C60 under ambient pressure were studied by X-ray diffraction (XRD) and ESR. The XRD showed that Cs3C60 takes a body-centered orthorhombic structure as the main phase. No clear structural change was observed down to 9 K. The temperature dependence of the ESR peak suggested that Cs3C60 exhibits a metallic behavior but no metal-insulator transition down to 1.9 K, contrary to a previous prediction.

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