Stereoselective synthesis and absolute configuration of the C1′-C25′ fragment of symbiodinolide

Hiroyoshi Takamura; Takeshi Murata; Takahiro Asai; Isao Kadota; Daisuke Uemura

doi:10.1021/jo901162v

Stereoselective synthesis and absolute configuration of the C1′-C25′ fragment of symbiodinolide

Hiroyoshi Takamura, Takeshi Murata, Takahiro Asai, Isao Kadota, Daisuke Uemura

研究成果 › 査読

18 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Stereoselective synthesis of the C1′-C25′ fragment of symbiodinolide, which was obtained as a degraded product from symbiodinolide by alkaline hydrolysis, has been accomplished. The synthetic route features Kotsuki coupling and Julia-Kocienski olefination in the introduction of the side chains. This enantioand stereoselective synthesis has established the absolute configuration of the C1′-C25′ fragment.

本文言語	English
ページ（範囲）	6658-6666
ページ数	9
ジャーナル	Journal of Organic Chemistry
巻	74
号	17
DOI	https://doi.org/10.1021/jo901162v
出版ステータス	Published - 9月 4 2009

ASJC Scopus subject areas

有機化学

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10.1021/jo901162v

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AU - Kadota, Isao

AU - Uemura, Daisuke

PY - 2009/9/4

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AB - (Chemical Equation Presented) Stereoselective synthesis of the C1′-C25′ fragment of symbiodinolide, which was obtained as a degraded product from symbiodinolide by alkaline hydrolysis, has been accomplished. The synthetic route features Kotsuki coupling and Julia-Kocienski olefination in the introduction of the side chains. This enantioand stereoselective synthesis has established the absolute configuration of the C1′-C25′ fragment.

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Stereoselective synthesis and absolute configuration of the C1′-C25′ fragment of symbiodinolide

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