Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

Takaya Mise; Yutaka Takaguchi; Takeshi Umemiya; Shoichi Shimizu; Yasuo Wakatsuki

doi:10.1039/a800293b

Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

Takaya Mise, Yutaka Takaguchi, Takeshi Umemiya, Shoichi Shimizu, Yasuo Wakatsuki

研究成果 › 査読

47 被引用数 (Scopus)

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Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.

本文言語	English
ページ（範囲）	699-700
ページ数	2
ジャーナル	Chemical Communications
号	6
DOI	https://doi.org/10.1039/a800293b
出版ステータス	Published - 3月 21 1998
外部発表	はい

ASJC Scopus subject areas

触媒
電子材料、光学材料、および磁性材料
セラミックおよび複合材料
化学 (全般)
表面、皮膜および薄膜
金属および合金
材料化学

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10.1039/a800293b

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abstract = "Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.",

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AU - Shimizu, Shoichi

AU - Wakatsuki, Yasuo

PY - 1998/3/21

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AB - Compounds having a vinyldimethylsilyl group at both terminals have been successfully cyclized by ruthenium hydride catalysts to give selectively disilacycles of various ring sizes via a metathetical reaction, i.e. ethene elimination from the two terminal vinyl groups, not involving metallocarbene-metallacyclobutane type intermediates.

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Ruthenium-catalyzed ring-closing reaction of α,ω-bis(vinylsilyl) compounds via a silyl transfer mechanism

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