Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace

Takahiro Ohkubo; Takehisa Konishi; Yoshiyuki Hattori; Hirofumi Kanoh; Takashi Fujikawa; Katsumi Kaneko

doi:10.1021/ja027144t

Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace

Takahiro Ohkubo, Takehisa Konishi, Yoshiyuki Hattori, Hirofumi Kanoh, Takashi Fujikawa, Katsumi Kaneko

研究成果 › 査読

94 被引用数 (Scopus)

抄録

Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.

本文言語	English
ページ（範囲）	11860-11861
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	124
号	40
DOI	https://doi.org/10.1021/ja027144t
出版ステータス	Published - 10月 9 2002
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

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10.1021/ja027144t

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abstract = "Hydration structures of {"}nanosolutions{"} around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.",

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T1 - Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace

AU - Ohkubo, Takahiro

AU - Konishi, Takehisa

AU - Hattori, Yoshiyuki

AU - Kanoh, Hirofumi

AU - Fujikawa, Takashi

AU - Kaneko, Katsumi

PY - 2002/10/9

Y1 - 2002/10/9

N2 - Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.

AB - Hydration structures of "nanosolutions" around both cation and anion for rubidium bromide confined in nanospaces (pore width = 1.1 nm) of activated carbon fiber were determined with EXAFS measurements and related analysis. The analytical results indicate that the ionic solutions confined in hydrophobic nanospaces tend to form an incomplete dehydration structure, because of the spatial restriction by the nanospace and capturing water molecules in the ordered structure.

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Restricted hydration structures of Rb and Br ions confined in slit-shaped carbon nanospace

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