Reactions of a N-acyliminium ion pool with benzylsilanes. Implication of a radical/cation/radical cation chain mechanism involving oxidative C-Si bond cleavage

Tomokazu Maruyama; Yusuke Mizuno; Ikuo Shimizu; Seiji Suga; Jun Ichi Yoshida

doi:10.1021/ja068589a

Reactions of a N-acyliminium ion pool with benzylsilanes. Implication of a radical/cation/radical cation chain mechanism involving oxidative C-Si bond cleavage

Tomokazu Maruyama, Yusuke Mizuno, Ikuo Shimizu, Seiji Suga, Jun Ichi Yoshida

研究成果 › 査読

76 被引用数 (Scopus)

抄録

The reaction of a N-acyliminium ion pool with benzylsilane proceeds by a chain mechanism involving oxidative C-Si bond cleavage. A radical/cation/radical cation crossover mechanism involving single electron transfer has been proposed. The effective binary system consisting of a stoichiometric amount of a benzylsilane and a catalytic amount of a more easily oxidized benzylstannane has been developed.

本文言語	English
ページ（範囲）	1902-1903
ページ数	2
ジャーナル	Journal of the American Chemical Society
巻	129
号	7
DOI	https://doi.org/10.1021/ja068589a
出版ステータス	Published - 2月 21 2007
外部発表	はい

ASJC Scopus subject areas

触媒
化学 (全般)
生化学
コロイド化学および表面化学

文献へのアクセス

10.1021/ja068589a

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引用スタイル

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