抄録
(Chemical Equation Presented) Neighboring-group participation of an acyl protecting group efficiently promotes the Brønsted acid-catalyzed dehydrative cyclization of 1,3,5-triketones to γ-pyrones, whereas a bulky silyloxy group in the β-position retards the cyclization. This reaction provides an efficient synthetic route for a common intermediate for the synthesis of γ-pyrone-containing bioactive natural products.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 2569-2572 |
| ページ数 | 4 |
| ジャーナル | Organic Letters |
| 巻 | 10 |
| 号 | 12 |
| DOI | |
| 出版ステータス | Published - 2008 |
| 外部発表 | はい |
ASJC Scopus subject areas
- 生化学
- 物理化学および理論化学
- 有機化学