Palladium-catalyzed addition of silyl-substituted chloroalkynes to terminal alkynes

Tatsuya Wada; Masayuki Iwasaki; Azusa Kondoh; Hideki Yorimitsu; Koichiro Oshima

doi:10.1002/chem.201000865

Palladium-catalyzed addition of silyl-substituted chloroalkynes to terminal alkynes

Tatsuya Wada, Masayuki Iwasaki, Azusa Kondoh, Hideki Yorimitsu, Koichiro Oshima

研究成果 › 査読

22 被引用数 (Scopus)

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Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented)

本文言語	English
ページ（範囲）	10671-10674
ページ数	4
ジャーナル	Chemistry - A European Journal
巻	16
号	35
DOI	https://doi.org/10.1002/chem.201000865
出版ステータス	Published - 9月 17 2010
外部発表	はい

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有機化学

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AU - Wada, Tatsuya

AU - Iwasaki, Masayuki

AU - Kondoh, Azusa

AU - Yorimitsu, Hideki

AU - Oshima, Koichiro

PY - 2010/9/17

Y1 - 2010/9/17

N2 - Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented)

AB - Better together: A novel hybrid N-heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi-turnover catalysis in C-C crosscoupling and aromatic dehalogenation reactions under MW-assisted protocols (see scheme). (Figure Presented)

KW - Addition reactions

KW - Alkynes

KW - Enynes

KW - Palladium synthetic methods

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Palladium-catalyzed addition of silyl-substituted chloroalkynes to terminal alkynes

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