TY - JOUR
T1 - One-pot substitution-rearrangement reaction of 2-chloroglycidic ester
T2 - Effective protocol for the preparation of 3-arylsulfenyl-2-keto ester
AU - Komiyama, Takuzo
AU - Takaguchi, Yutaka
AU - Tsuboi, Sadao
PY - 2006/1/1
Y1 - 2006/1/1
N2 - The one-pot substitution-rearrangement reaction of 2-chloroglycidic ester is reported. Treatment of 2-chloroglycidic ester with sodium arylthiolate at room temperature results in the formation of 3-arylsulfenyl-2-keto ester in excellent to good yields.
AB - The one-pot substitution-rearrangement reaction of 2-chloroglycidic ester is reported. Treatment of 2-chloroglycidic ester with sodium arylthiolate at room temperature results in the formation of 3-arylsulfenyl-2-keto ester in excellent to good yields.
KW - 2-Chloroglycidic ester
KW - Darzens condensation
KW - Dichloroacetate
KW - Substitution-rearrangement reaction
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U2 - 10.1080/00397910500374914
DO - 10.1080/00397910500374914
M3 - Article
AN - SCOPUS:31544477760
SN - 0039-7911
VL - 36
SP - 265
EP - 269
JO - Synthetic Communications
JF - Synthetic Communications
IS - 3
ER -