TY - JOUR
T1 - Hydrogen partitioning into molten iron at high pressure
T2 - Implications for earth's core
AU - Okuchi, Takuo
PY - 1997/12/5
Y1 - 1997/12/5
N2 - Because of dissolution of lighter elements such as sulfur, carbon, hydrogen, and oxygen, Earth's outer core is about 10 percent less dense than molten iron at the relevant pressure and temperature conditions. To determine whether hydrogen can account for a major part of the density deficit and is therefore an important constituent in the molten iron outer core, the hydrogen concentration in molten iron was measured at 7.5 gigapascals. From these measurements, the metal-silicate melt partitioning coefficient of hydrogen was determined as a function of temperature. If the magma ocean of primordial Earth was hydrous, more than 95 mole percent of H2O in this ocean should have reacted with iron to form Felix, and about 60 percent of the density deficit is reconciled by adding hydrogen to the core.
AB - Because of dissolution of lighter elements such as sulfur, carbon, hydrogen, and oxygen, Earth's outer core is about 10 percent less dense than molten iron at the relevant pressure and temperature conditions. To determine whether hydrogen can account for a major part of the density deficit and is therefore an important constituent in the molten iron outer core, the hydrogen concentration in molten iron was measured at 7.5 gigapascals. From these measurements, the metal-silicate melt partitioning coefficient of hydrogen was determined as a function of temperature. If the magma ocean of primordial Earth was hydrous, more than 95 mole percent of H2O in this ocean should have reacted with iron to form Felix, and about 60 percent of the density deficit is reconciled by adding hydrogen to the core.
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U2 - 10.1126/science.278.5344.1781
DO - 10.1126/science.278.5344.1781
M3 - Review article
AN - SCOPUS:0030720086
SN - 0036-8075
VL - 278
SP - 1781
EP - 1784
JO - Science
JF - Science
IS - 5344
ER -