抄録
Electro-oxidative kinetic resolution of sec-alcohols mediated with a catalytic amount of an optically active N-oxyl was performed by use of a simple undivided cell under constant current conditions. The selectivity factor (S-value) increased remarkably when the reaction was performed at lower temperatures. The optically active N-oxyl was recovered and used repeatedly without any change in efficiency and selectivity.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 8131-8135 |
| ページ数 | 5 |
| ジャーナル | Tetrahedron Letters |
| 巻 | 41 |
| 号 | 42 |
| DOI | |
| 出版ステータス | Published - 10月 14 2000 |
ASJC Scopus subject areas
- 生化学
- 創薬
- 有機化学