@article{146c02e585a4458099e75dec2d65f88a,
title = "Acylative desymmetrization of glycerol derivatives by chiral dmap derivatives",
abstract = "An efficient enantioselective acylative desymmetrization of glycerol was developed by using a chiral DMAP derivatives 1e having a 1,1-binaphthyl unit. The reactions required only 0.1 mol% of the catalyst and showed moderate to good enantioselectivity (up to 94:6 er). Control experiments revealed that the first acylation of a glycerol derivative proceeded selectively rather than the second acylation to give diacylate.",
author = "Hiroki Mandai and Kosuke Ashihara and Koichi Mitsudo and Seiji Suga",
note = "Funding Information: This research was partially supported by the Japan Soap and Detergent Association (JSDA) and JSPS Kakenhi Grant Number JP19K05456. Publisher Copyright: {\textcopyright} 2021 The Japan Institute of Heterocyclic Chemistry",
year = "2021",
doi = "10.3987/COM-21-14433",
language = "English",
volume = "102",
pages = "1083--1090",
journal = "Heterocycles",
issn = "0385-5414",
publisher = "Japan Institute of Heterocyclic Chemistry",
number = "6",
}