A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX2-TiCl4-Zn Systems by Addition of Lead

Kazuhiko Takai; Tadahiro Kakiuchi; Yasutaka Kataoka; Kiitiro Utimoto

doi:10.1021/jo00089a002

A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX₂-TiCl₄-Zn Systems by Addition of Lead

Kazuhiko Takai, Tadahiro Kakiuchi, Yasutaka Kataoka, Kiitiro Utimoto

研究成果 › 査読

244 被引用数 (Scopus)

抄録

A catalytic amount of lead promotes further reduction of zinc carbenoid (ICH₃ZnI) with zinc in THF to give a geminal dizinc compound (CH₂(ZnI)₂), which is a key intermediate for the methylenation of carbonyl compounds with a CH₂I₂, zinc, and TiCl₄ system.

本文言語	English
ページ（範囲）	2668-2670
ページ数	3
ジャーナル	Journal of Organic Chemistry
巻	59
号	10
DOI	https://doi.org/10.1021/jo00089a002
出版ステータス	Published - 5月 1 1994

ASJC Scopus subject areas

有機化学

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10.1021/jo00089a002

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「A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX₂-TiCl₄-Zn Systems by Addition of Lead」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX₂-TiCl₄-Zn Systems by Addition of Lead. / Takai, Kazuhiko; Kakiuchi, Tadahiro; Kataoka, Yasutaka その他.

In: Journal of Organic Chemistry, Vol. 59, No. 10, 01.05.1994, p. 2668-2670.

研究成果 › 査読

Takai, K, Kakiuchi, T, Kataoka, Y & Utimoto, K 1994, 'A Novel Catalytic Effect of Lead on the Reduction of a Zinc Carbenoid with Zinc Metal Leading to a Geminal Dizinc Compound. Acceleration of the Wittig-Type Olefination with the RCHX₂-TiCl₄-Zn Systems by Addition of Lead', Journal of Organic Chemistry, vol. 59, no. 10, pp. 2668-2670. https://doi.org/10.1021/jo00089a002

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abstract = "A catalytic amount of lead promotes further reduction of zinc carbenoid (ICH3ZnI) with zinc in THF to give a geminal dizinc compound (CH2(ZnI)2), which is a key intermediate for the methylenation of carbonyl compounds with a CH2I2, zinc, and TiCl4 system.",

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