A facile synthesis of trifluoromethyl- and 3,3,3-trifluoropropenyl- substituted aromatic compounds by the oxidative desulfurization-fluorination of the corresponding carbodithioates

Satoru Furuta, Manabu Kuroboshi, Tamejiro Hiyama

研究成果査読

32 被引用数 (Scopus)

抄録

Trifluoromethyl-substituted aromatic compounds were easily synthesized by the oxidative desulfurization-fluorination reaction of readily accessible methyl arenecarbodithioates using [n-Bu4N]H2F3 and 1,3-dibromo-5,5- dimethylhydantoin (DBH) under extremely mild conditions. Use of N- bromosuccinimide or N-iodosuccinimide instead of DBH afforded difluoro(methylthio)methyl-substituted aromatics. In a similar way, 3,3,3- trifluoropropenyl-substituted aromatic compounds were readily prepared from the corresponding α,β-unsaturated carbodithioates.

本文言語English
ページ(範囲)805-819
ページ数15
ジャーナルBulletin of the Chemical Society of Japan
72
4
DOI
出版ステータスPublished - 4月 1 1999

ASJC Scopus subject areas

  • 化学 (全般)

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