X-ray spectroscopy study on the electronic structure of hole-doped edge-shared chains in Ca2+xY2-xCu5O10

Eiki Kabasawa, Jin Nakamura, Takashi Morimoto, Nobuyoshi Yamada, Kazuhiko Kuroki, Hisashi Yamazaki, Kozo Okada, Kunihiko Oka, Yasuhisa Tezuka, Jonathan D. Denlinger, Rupert C C Perera

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

X-ray absorption (XAS) and emission (XES) spectroscopy near O K edge has been performed on edge-shared CuO chain compounds Ca2+xY2-xCu 5O10 (0.0≤x≤2.0) using poly- and single-crystalline samples. Two large peaks are observed at 528 eV (PH) and 530 eV (P U) in the XAS spectra. The intensity of the PH peak monotonically increases and that of the PU monotonically decreases with hole doping. The two characteristic peaks in the XAS spectra at P H and PU, which are assigned for the polycrystalline samples to the hole and upper Hubbard band (UHB) states, respectively. The theoretical calculations reproduce the experimental XAS results, especially that the PU peak decreases by hole doping. The spectral weight transfer from the PU peak to the PH peak of the edge-shared chain by hole doping is strongly suppressed in comparison with that of the CuO 2 plane. From the single crystal measurements of undoped Ca 2Y2Cu5O10, the spectra of XAS and XES are interpreted in terms of a square-like CuO4 plaquette for the compound. As for the hole-doped Ca3YCu5O10 sample, the plaquette containing a doped hole is found to be square-like, and the plaquettes with no doped holes are found to be rectangle-like. We concluded that the doped hole is localized associated with the lattice deformation. The electric properties are discussed based on our result.

Original languageEnglish
Pages (from-to)65-72
Number of pages8
JournalJournal of Electron Spectroscopy and Related Phenomena
Volume148
Issue number1
DOIs
Publication statusPublished - Jul 2005

Fingerprint

X ray absorption
X ray spectroscopy
Electronic structure
electronic structure
Doping (additives)
spectroscopy
Absorption spectra
x rays
X ray absorption spectroscopy
Electric properties
Single crystals
Crystalline materials
absorption spectra
rectangles
single crystals

Keywords

  • Edge-shared chain
  • Localized hole
  • One-dimensional cuprate
  • XAS
  • XES

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

X-ray spectroscopy study on the electronic structure of hole-doped edge-shared chains in Ca2+xY2-xCu5O10. / Kabasawa, Eiki; Nakamura, Jin; Morimoto, Takashi; Yamada, Nobuyoshi; Kuroki, Kazuhiko; Yamazaki, Hisashi; Okada, Kozo; Oka, Kunihiko; Tezuka, Yasuhisa; Denlinger, Jonathan D.; Perera, Rupert C C.

In: Journal of Electron Spectroscopy and Related Phenomena, Vol. 148, No. 1, 07.2005, p. 65-72.

Research output: Contribution to journalArticle

Kabasawa, E, Nakamura, J, Morimoto, T, Yamada, N, Kuroki, K, Yamazaki, H, Okada, K, Oka, K, Tezuka, Y, Denlinger, JD & Perera, RCC 2005, 'X-ray spectroscopy study on the electronic structure of hole-doped edge-shared chains in Ca2+xY2-xCu5O10', Journal of Electron Spectroscopy and Related Phenomena, vol. 148, no. 1, pp. 65-72. https://doi.org/10.1016/j.elspec.2005.03.001
Kabasawa, Eiki ; Nakamura, Jin ; Morimoto, Takashi ; Yamada, Nobuyoshi ; Kuroki, Kazuhiko ; Yamazaki, Hisashi ; Okada, Kozo ; Oka, Kunihiko ; Tezuka, Yasuhisa ; Denlinger, Jonathan D. ; Perera, Rupert C C. / X-ray spectroscopy study on the electronic structure of hole-doped edge-shared chains in Ca2+xY2-xCu5O10. In: Journal of Electron Spectroscopy and Related Phenomena. 2005 ; Vol. 148, No. 1. pp. 65-72.
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abstract = "X-ray absorption (XAS) and emission (XES) spectroscopy near O K edge has been performed on edge-shared CuO chain compounds Ca2+xY2-xCu 5O10 (0.0≤x≤2.0) using poly- and single-crystalline samples. Two large peaks are observed at 528 eV (PH) and 530 eV (P U) in the XAS spectra. The intensity of the PH peak monotonically increases and that of the PU monotonically decreases with hole doping. The two characteristic peaks in the XAS spectra at P H and PU, which are assigned for the polycrystalline samples to the hole and upper Hubbard band (UHB) states, respectively. The theoretical calculations reproduce the experimental XAS results, especially that the PU peak decreases by hole doping. The spectral weight transfer from the PU peak to the PH peak of the edge-shared chain by hole doping is strongly suppressed in comparison with that of the CuO 2 plane. From the single crystal measurements of undoped Ca 2Y2Cu5O10, the spectra of XAS and XES are interpreted in terms of a square-like CuO4 plaquette for the compound. As for the hole-doped Ca3YCu5O10 sample, the plaquette containing a doped hole is found to be square-like, and the plaquettes with no doped holes are found to be rectangle-like. We concluded that the doped hole is localized associated with the lattice deformation. The electric properties are discussed based on our result.",
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AU - Yamada, Nobuyoshi

AU - Kuroki, Kazuhiko

AU - Yamazaki, Hisashi

AU - Okada, Kozo

AU - Oka, Kunihiko

AU - Tezuka, Yasuhisa

AU - Denlinger, Jonathan D.

AU - Perera, Rupert C C

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AB - X-ray absorption (XAS) and emission (XES) spectroscopy near O K edge has been performed on edge-shared CuO chain compounds Ca2+xY2-xCu 5O10 (0.0≤x≤2.0) using poly- and single-crystalline samples. Two large peaks are observed at 528 eV (PH) and 530 eV (P U) in the XAS spectra. The intensity of the PH peak monotonically increases and that of the PU monotonically decreases with hole doping. The two characteristic peaks in the XAS spectra at P H and PU, which are assigned for the polycrystalline samples to the hole and upper Hubbard band (UHB) states, respectively. The theoretical calculations reproduce the experimental XAS results, especially that the PU peak decreases by hole doping. The spectral weight transfer from the PU peak to the PH peak of the edge-shared chain by hole doping is strongly suppressed in comparison with that of the CuO 2 plane. From the single crystal measurements of undoped Ca 2Y2Cu5O10, the spectra of XAS and XES are interpreted in terms of a square-like CuO4 plaquette for the compound. As for the hole-doped Ca3YCu5O10 sample, the plaquette containing a doped hole is found to be square-like, and the plaquettes with no doped holes are found to be rectangle-like. We concluded that the doped hole is localized associated with the lattice deformation. The electric properties are discussed based on our result.

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