W(CO)5(L)-promoted cyclization of 1-iodo-1-alkynes via iodovinylidene tungsten complexes

Tomoya Miura, Hiroaki Murata, Koichi Kiyota, Hiroyuki Kusama, Nobuharu Iwasawa

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)

Abstract

Iodovinylidene tungsten complexes are generated from 1-iodo-1-alkynes and W(CO)5(thf), and are employed for two types of synthetically useful reaction, that is, 6π-electrocyclization for o-(iodoethynyl)styrenes, and endo-selective cyclization for ω-iodoacetylenic silyl enol ethers and 1-iodo-5-en-1-yne.

Original languageEnglish
Pages (from-to)59-71
Number of pages13
JournalJournal of Molecular Catalysis A: Chemical
Volume213
Issue number1
DOIs
Publication statusPublished - Apr 13 2004
Externally publishedYes

Keywords

  • π-Electrocyclization
  • 1-Iodo-1-alkynes
  • Endo-selective cyclization
  • Iodovinylidene tungsten complex
  • Trimethylsilylvinylidene rhodium complexes

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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