Water-soluble N-oxyl compounds-mediated electrooxidation of alcohols in water: A prominent access to a totally closed system

Jun Kubota; Yusuke Shimizu; Koichi Mitsudo; Hideo Tanaka

doi:10.1016/j.tetlet.2005.10.114

Water-soluble N-oxyl compounds-mediated electrooxidation of alcohols in water: A prominent access to a totally closed system

Jun Kubota, Yusuke Shimizu, Koichi Mitsudo, Hideo Tanaka

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Electrooxidation of alcohols in water involving water-soluble N-oxyl compounds (WS-TEMPOs) proceeded smoothly to afford the corresponding ketones and aldehydes in good yields. Notably, most of WS-TEMPOs in water remained intact after the electrolysis. The aqueous solution containing WS-TEMPOs was recovered easily and repeatedly used for the electrooxidation of alcohols, offering a totally closed system.

Original language	English
Pages (from-to)	8975-8979
Number of pages	5
Journal	Tetrahedron Letters
Volume	46
Issue number	52
DOIs	https://doi.org/10.1016/j.tetlet.2005.10.114
Publication status	Published - Dec 26 2005

Keywords

Alcohols
Aqueous solution
Electrooxidation
N-Oxyl compounds
Water-soluble mediators

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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abstract = "Electrooxidation of alcohols in water involving water-soluble N-oxyl compounds (WS-TEMPOs) proceeded smoothly to afford the corresponding ketones and aldehydes in good yields. Notably, most of WS-TEMPOs in water remained intact after the electrolysis. The aqueous solution containing WS-TEMPOs was recovered easily and repeatedly used for the electrooxidation of alcohols, offering a totally closed system.",

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T1 - Water-soluble N-oxyl compounds-mediated electrooxidation of alcohols in water

T2 - A prominent access to a totally closed system

AU - Kubota, Jun

AU - Shimizu, Yusuke

AU - Mitsudo, Koichi

AU - Tanaka, Hideo

PY - 2005/12/26

Y1 - 2005/12/26

N2 - Electrooxidation of alcohols in water involving water-soluble N-oxyl compounds (WS-TEMPOs) proceeded smoothly to afford the corresponding ketones and aldehydes in good yields. Notably, most of WS-TEMPOs in water remained intact after the electrolysis. The aqueous solution containing WS-TEMPOs was recovered easily and repeatedly used for the electrooxidation of alcohols, offering a totally closed system.

AB - Electrooxidation of alcohols in water involving water-soluble N-oxyl compounds (WS-TEMPOs) proceeded smoothly to afford the corresponding ketones and aldehydes in good yields. Notably, most of WS-TEMPOs in water remained intact after the electrolysis. The aqueous solution containing WS-TEMPOs was recovered easily and repeatedly used for the electrooxidation of alcohols, offering a totally closed system.

KW - Alcohols

KW - Aqueous solution

KW - Electrooxidation

KW - N-Oxyl compounds

KW - Water-soluble mediators

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 52

ER -

Water-soluble N-oxyl compounds-mediated electrooxidation of alcohols in water: A prominent access to a totally closed system

Abstract

Keywords

ASJC Scopus subject areas

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