Water Concentration in Single-Crystal (Al,Fe)-Bearing Bridgmanite Grown From the Hydrous Melt: Implications for Dehydration Melting at the Topmost Lower Mantle

Suyu Fu, Jing Yang, Shun ichiro Karato, Alexander Vasiliev, Mikhail Yu Presniakov, Alexander G. Gavrilliuk, Anna G. Ivanova, Erik H. Hauri, Takuo Okuchi, Narangoo Purevjav, Jung Fu Lin

Research output: Contribution to journalArticle

Abstract

High-quality single-crystals of (Al,Fe)-bearing bridgmanite, Mg0.88 Fe3+ 0.065Fe2+ 0.035Al0.14Si0.90O3, of hundreds of micrometer size were synthesized at 24 GPa and 1800 °C in a Kawai-type apparatus from the starting hydrous melt containing ~6.7 wt% water. Analyses of synthesized bridgmanite using petrographic microscopy, scanning electron microscopy, and transmission electron microscopy show that the crystals are chemically homogeneous and inclusion free in micrometer- to nanometer-spatial resolutions. Nanosecondary ion mass spectrometry (NanoSIMS) analyses on selected platelets show ~1,020(±70) ppm wt water (hydrogen). The high water concentration in the structure of bridgmanite was further confirmed using polarized and unpolarized Fourier-transform infrared spectroscopy (FTIR) analyses with two pronounced OH-stretching bands at ~3,230 and ~3,460 cm−1. Our results indicate that lower-mantle bridgmanite can accommodate relatively high amount of water. Therefore, dehydration melting at the topmost lower mantle by downward flow of transition zone materials would require water content exceeding ~0.1 wt%.

Original languageEnglish
JournalGeophysical Research Letters
DOIs
Publication statusAccepted/In press - Jan 1 2019

Fingerprint

dehydration melting
lower mantle
dehydration
Earth mantle
melting
melt
crystal
single crystals
water
micrometers
platelets
FTIR spectroscopy
transition zone
moisture content
transmission electron microscopy
microscopy
spatial resolution
mass spectroscopy
mass spectrometry
scanning electron microscopy

Keywords

  • dehydration melting
  • lower mantle
  • single-crystal bridgmanite
  • transition zone
  • water solubility

ASJC Scopus subject areas

  • Geophysics
  • Earth and Planetary Sciences(all)

Cite this

Water Concentration in Single-Crystal (Al,Fe)-Bearing Bridgmanite Grown From the Hydrous Melt : Implications for Dehydration Melting at the Topmost Lower Mantle. / Fu, Suyu; Yang, Jing; Karato, Shun ichiro; Vasiliev, Alexander; Presniakov, Mikhail Yu; Gavrilliuk, Alexander G.; Ivanova, Anna G.; Hauri, Erik H.; Okuchi, Takuo; Purevjav, Narangoo; Lin, Jung Fu.

In: Geophysical Research Letters, 01.01.2019.

Research output: Contribution to journalArticle

Fu, Suyu ; Yang, Jing ; Karato, Shun ichiro ; Vasiliev, Alexander ; Presniakov, Mikhail Yu ; Gavrilliuk, Alexander G. ; Ivanova, Anna G. ; Hauri, Erik H. ; Okuchi, Takuo ; Purevjav, Narangoo ; Lin, Jung Fu. / Water Concentration in Single-Crystal (Al,Fe)-Bearing Bridgmanite Grown From the Hydrous Melt : Implications for Dehydration Melting at the Topmost Lower Mantle. In: Geophysical Research Letters. 2019.
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abstract = "High-quality single-crystals of (Al,Fe)-bearing bridgmanite, Mg0.88 Fe3+ 0.065Fe2+ 0.035Al0.14Si0.90O3, of hundreds of micrometer size were synthesized at 24 GPa and 1800 °C in a Kawai-type apparatus from the starting hydrous melt containing ~6.7 wt{\%} water. Analyses of synthesized bridgmanite using petrographic microscopy, scanning electron microscopy, and transmission electron microscopy show that the crystals are chemically homogeneous and inclusion free in micrometer- to nanometer-spatial resolutions. Nanosecondary ion mass spectrometry (NanoSIMS) analyses on selected platelets show ~1,020(±70) ppm wt water (hydrogen). The high water concentration in the structure of bridgmanite was further confirmed using polarized and unpolarized Fourier-transform infrared spectroscopy (FTIR) analyses with two pronounced OH-stretching bands at ~3,230 and ~3,460 cm−1. Our results indicate that lower-mantle bridgmanite can accommodate relatively high amount of water. Therefore, dehydration melting at the topmost lower mantle by downward flow of transition zone materials would require water content exceeding ~0.1 wt{\%}.",
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author = "Suyu Fu and Jing Yang and Karato, {Shun ichiro} and Alexander Vasiliev and Presniakov, {Mikhail Yu} and Gavrilliuk, {Alexander G.} and Ivanova, {Anna G.} and Hauri, {Erik H.} and Takuo Okuchi and Narangoo Purevjav and Lin, {Jung Fu}",
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AU - Yang, Jing

AU - Karato, Shun ichiro

AU - Vasiliev, Alexander

AU - Presniakov, Mikhail Yu

AU - Gavrilliuk, Alexander G.

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AU - Lin, Jung Fu

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