Volume loss and metasomatism during cleavage formation in carbonate rocks

Scot G. Davidson, David J. Anastasio, Gray Edward Bebout, James E. Holl, Christopher A. Hedlund

Research output: Contribution to journalArticle

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Abstract

Controversy exists regarding the amount of volume loss associated with cleavage development. A combination of geometrical and geochemical techniques provides evidence for contemporaneous passive concentration (volume loss) and metasomatism leading to the formation of cleavage in carbonate lithologies and emphasizes the relationship between observational scales and textural heterogeneity. Comparison of protoliths and weakly- to strongly-cleaved rocks along steep, layer-parallel strain gradients within the Doublespring duplex, Lost River Range, Idaho, enables quantitative assessments of geometric transformation and elemental mass transfer accompanying progressive deformation. Geometric finite strain analysis documents shortening in the Z direction at low strains (̄εs <0.15) and in both the Z and Y directions at higher strains (̄εS >0.15). Unbalanced shortening in Z and Y with extension in X results in volume loss. Geometrically derived volume strain estimates at the 1-4 cm3 scale indicate volumetric dilations of from -2% to -12% in uncleaved to weakly-cleaved rocks, and from -20% to -50% in strongly- to very strongly-cleaved rocks. Small-scale significant volume losses and gains contrast with the estimated volume loss of <3% associated with duplex formation at the 100 km3-1 km3 scale due to the localization of strain within thin deformation zones. Sampling scale is also a factor in evaluating the major and trace element and O and C isotope compositions of the variably deformed rocks. Samples collected at the 4-15 cm3 scale reflect mixtures of chemically and mineralogically distinct selvage and microlithon domains. Microdrilling of samples at scales of a few cubic millimeters to 1 cm3 affords examination of chemical and isotopic differences among individual selvages and microlithons. The data for microdrilled samples demonstrate depletion of Ca and 18O and enrichment of K, Al, Si, Ti, Fe, Na, Mg and P in selvages relative to microlithons and nearby undeformed carbonate layers. The enrichments of some elements (Mg, P, Na and possibly Fe) are more compatible with a passive concentration mechanism, whereas the concentrations of other elements, particularly K, Al, Si and Ti, require significant metasomatic addition during deformation. Shifts in O-isotope compositions of deformed samples relative to the protolith δ18O values unequivocally demonstrate open-system behavior during deformation. Trends of deformed samples toward lower δ18O with increasing strain and the δ18O values of veins are compatible with infiltration by H2O-rich fluids with relatively low δ18OV-SMOW (near 0‰). The formation of disjunctive cleavage at the Doublespring duplex occurred by passive concentration resulting from calcite dissolution and related volume loss, and neo-crystallization of illite + kaolinite + quartz ± anatase in selvages as a result of metasomatic additions. Chemical and geometric strain softening within selvages likely led to enhanced and preferential fluid flow in selvages.

Original languageEnglish
Pages (from-to)707-726
Number of pages20
JournalJournal of Structural Geology
Volume20
Issue number6
DOIs
Publication statusPublished - Jun 1998
Externally publishedYes

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metasomatism
carbonate rock
cleavage
duplex
protolith
rock
isotope
carbonate
strain analysis
anatase
preferential flow
dilation
loss
softening
illite
kaolinite
fluid flow
mass transfer
lithology
crystallization

ASJC Scopus subject areas

  • Geology

Cite this

Volume loss and metasomatism during cleavage formation in carbonate rocks. / Davidson, Scot G.; Anastasio, David J.; Edward Bebout, Gray; Holl, James E.; Hedlund, Christopher A.

In: Journal of Structural Geology, Vol. 20, No. 6, 06.1998, p. 707-726.

Research output: Contribution to journalArticle

Davidson, Scot G. ; Anastasio, David J. ; Edward Bebout, Gray ; Holl, James E. ; Hedlund, Christopher A. / Volume loss and metasomatism during cleavage formation in carbonate rocks. In: Journal of Structural Geology. 1998 ; Vol. 20, No. 6. pp. 707-726.
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N2 - Controversy exists regarding the amount of volume loss associated with cleavage development. A combination of geometrical and geochemical techniques provides evidence for contemporaneous passive concentration (volume loss) and metasomatism leading to the formation of cleavage in carbonate lithologies and emphasizes the relationship between observational scales and textural heterogeneity. Comparison of protoliths and weakly- to strongly-cleaved rocks along steep, layer-parallel strain gradients within the Doublespring duplex, Lost River Range, Idaho, enables quantitative assessments of geometric transformation and elemental mass transfer accompanying progressive deformation. Geometric finite strain analysis documents shortening in the Z direction at low strains (̄εs <0.15) and in both the Z and Y directions at higher strains (̄εS >0.15). Unbalanced shortening in Z and Y with extension in X results in volume loss. Geometrically derived volume strain estimates at the 1-4 cm3 scale indicate volumetric dilations of from -2% to -12% in uncleaved to weakly-cleaved rocks, and from -20% to -50% in strongly- to very strongly-cleaved rocks. Small-scale significant volume losses and gains contrast with the estimated volume loss of <3% associated with duplex formation at the 100 km3-1 km3 scale due to the localization of strain within thin deformation zones. Sampling scale is also a factor in evaluating the major and trace element and O and C isotope compositions of the variably deformed rocks. Samples collected at the 4-15 cm3 scale reflect mixtures of chemically and mineralogically distinct selvage and microlithon domains. Microdrilling of samples at scales of a few cubic millimeters to 1 cm3 affords examination of chemical and isotopic differences among individual selvages and microlithons. The data for microdrilled samples demonstrate depletion of Ca and 18O and enrichment of K, Al, Si, Ti, Fe, Na, Mg and P in selvages relative to microlithons and nearby undeformed carbonate layers. The enrichments of some elements (Mg, P, Na and possibly Fe) are more compatible with a passive concentration mechanism, whereas the concentrations of other elements, particularly K, Al, Si and Ti, require significant metasomatic addition during deformation. Shifts in O-isotope compositions of deformed samples relative to the protolith δ18O values unequivocally demonstrate open-system behavior during deformation. Trends of deformed samples toward lower δ18O with increasing strain and the δ18O values of veins are compatible with infiltration by H2O-rich fluids with relatively low δ18OV-SMOW (near 0‰). The formation of disjunctive cleavage at the Doublespring duplex occurred by passive concentration resulting from calcite dissolution and related volume loss, and neo-crystallization of illite + kaolinite + quartz ± anatase in selvages as a result of metasomatic additions. Chemical and geometric strain softening within selvages likely led to enhanced and preferential fluid flow in selvages.

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