Visible light photocatalytic water splitting for hydrogen production from N-TiO 2 rice grain shaped electrospun nanostructures

Veluru Jagadeesh Babu, Manippady K. Kumar, Appukuttan Sreekumaran Nair, Tan Lee Kheng, Suleyman Allakhverdiev, Seeram Ramakrishna

Research output: Contribution to journalArticle

109 Citations (Scopus)

Abstract

We report on the visible light-driven hydrogen production from splitting of water molecules by nitrogen-doped TiO 2 (N-TiO 2) with a rice grain-like nanostructure morphology. The N-TiO 2 nanostructures are prepared using sol-gel and electrospinning methods followed by post-annealing of the composite nanofibers. The nanostructures are characterized by microscopy and spectroscopy. First order rate constants for the visible light-assisted photocatalysis in the degradation of methylene blue (MB) dye are found to be 0.2 × 10 -3 and 1.8 × 10 -3 min -1 for TiO 2 and N-TiO 2 (5 wt% of nitrogen), respectively. The N-TiO 2 utilized in water splitting experiments and evaluated hydrogen (H 2) of 28 and 2 μmol/h for N-TiO 2 and TiO 2, respectively. The improvement may be attributed due to the N-doping and higher surface area as ∼70 m 2/g.

Original languageEnglish
Pages (from-to)8897-8904
Number of pages8
JournalInternational Journal of Hydrogen Energy
Volume37
Issue number10
DOIs
Publication statusPublished - May 1 2012
Externally publishedYes

Fingerprint

light water
water splitting
hydrogen production
rice
Hydrogen production
Nanostructures
Nitrogen
nitrogen
Water
Hydrogen
Photocatalysis
methylene blue
Electrospinning
Nanofibers
Sol-gels
Rate constants
Microscopic examination
Dyes
dyes
Doping (additives)

Keywords

  • Electrospinning
  • H production
  • Hybrid nanostructures
  • Photocatalysis

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Fuel Technology
  • Condensed Matter Physics
  • Energy Engineering and Power Technology

Cite this

Visible light photocatalytic water splitting for hydrogen production from N-TiO 2 rice grain shaped electrospun nanostructures. / Babu, Veluru Jagadeesh; Kumar, Manippady K.; Nair, Appukuttan Sreekumaran; Kheng, Tan Lee; Allakhverdiev, Suleyman; Ramakrishna, Seeram.

In: International Journal of Hydrogen Energy, Vol. 37, No. 10, 01.05.2012, p. 8897-8904.

Research output: Contribution to journalArticle

Babu, Veluru Jagadeesh ; Kumar, Manippady K. ; Nair, Appukuttan Sreekumaran ; Kheng, Tan Lee ; Allakhverdiev, Suleyman ; Ramakrishna, Seeram. / Visible light photocatalytic water splitting for hydrogen production from N-TiO 2 rice grain shaped electrospun nanostructures. In: International Journal of Hydrogen Energy. 2012 ; Vol. 37, No. 10. pp. 8897-8904.
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