Viologen as catalytic organic reductant

Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system

Manabu Kuroboshi, Takuya Shiba, Hideo Tanaka

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Viologen can be used as an in situ recyclable organic reductant. Pd-catalyzed electrochemical reductive coupling of aryl bromides was performed by using a catalytic amount of viologen to afford the corresponding biaryls in good to moderate yields.

Original languageEnglish
Pages (from-to)3666-3668
Number of pages3
JournalTetrahedron Letters
Volume54
Issue number28
DOIs
Publication statusPublished - Jul 10 2013

Fingerprint

Viologens
Dimerization
Reducing Agents
Bromides

Keywords

  • Electroreduction
  • Mediatory system
  • Pd catalyst
  • Reductive coupling of aryl halide
  • Viologen

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Viologen as catalytic organic reductant : Electro-reductive dimerization of aryl bromides in a Pd/viologen double mediatory system. / Kuroboshi, Manabu; Shiba, Takuya; Tanaka, Hideo.

In: Tetrahedron Letters, Vol. 54, No. 28, 10.07.2013, p. 3666-3668.

Research output: Contribution to journalArticle

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