Vinylcyclopropanation of olefins via 3-methoxy-1-propenylrhodium(I)

Tomoya Miura, Taisuke Sasaki, Tatsuro Harumashi, Masahiro Murakami

Research output: Contribution to journalArticlepeer-review

49 Citations (Scopus)

Abstract

New cyclization reactions forming vinylcyclopropanes were developed wherein an alkenylrhodium(I) possessing a methoxy group at the allylic position as a potential leaving group acts as an allylic carbene equivalent. By this protocol, a vinylcyclopropane was installed in a complex cyclic structure in a single operation via successive multiple carbon-carbon bond formations.

Original languageEnglish
Pages (from-to)2516-2517
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number8
DOIs
Publication statusPublished - Mar 1 2006
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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