Use of aluminium as an electron pool. Reductive coupling of iodobenzenes promoted by electron transfer in an Ni/Pb/A1 multi redox system

Hideo Tanaka, Shin ichi Sumida, Noriko Kobayashi, Naoki Komatsu, Sigeru Torii

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

Reductive coupling of iodobenzenes was achieved successfully by use of a stoichiometric amount of aluminium metal as an electron source and catalytic amounts of NiCl2(bpy) (bpy=2,2 - ́bipyridyl) and lead(II) bromide as electron transfer catalysts in methanol containing potassium iodide.

Original languageEnglish
Pages (from-to)323-325
Number of pages3
JournalInorganica Chimica Acta
Volume222
Issue number1-2
DOIs
Publication statusPublished - 1994

Fingerprint

Iodobenzenes
Potassium iodide
potassium iodides
Potassium Iodide
Electron sources
2,2'-Dipyridyl
electron sources
Aluminum
Bromides
Oxidation-Reduction
Methanol
bromides
electron transfer
methyl alcohol
Lead
Metals
Electrons
aluminum
catalysts
Catalysts

Keywords

  • Aluminium complexes
  • Electron transfer catalyst
  • Lead complexes
  • Multi metal redox system
  • Nickel complexes
  • Reductive coupling of iodobenzenes

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Use of aluminium as an electron pool. Reductive coupling of iodobenzenes promoted by electron transfer in an Ni/Pb/A1 multi redox system. / Tanaka, Hideo; Sumida, Shin ichi; Kobayashi, Noriko; Komatsu, Naoki; Torii, Sigeru.

In: Inorganica Chimica Acta, Vol. 222, No. 1-2, 1994, p. 323-325.

Research output: Contribution to journalArticle

Tanaka, Hideo ; Sumida, Shin ichi ; Kobayashi, Noriko ; Komatsu, Naoki ; Torii, Sigeru. / Use of aluminium as an electron pool. Reductive coupling of iodobenzenes promoted by electron transfer in an Ni/Pb/A1 multi redox system. In: Inorganica Chimica Acta. 1994 ; Vol. 222, No. 1-2. pp. 323-325.
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