Unusual metal-dependent acceleration and deceleration in the metal-catalyzed hydrosilylation of olefin using pyridyldimethylsilanes

Kenichiro Itami, Koichi Mitsudo, Akira Nishino, Jun Ichi Yoshida

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The Rh- and Pt-catalyzed hydrosilylations of olefin utilizing 2-pyridyl-, 3-pyridyl-, 4-pyridyl-, and phenyldimethylsilane are described. Whereas huge rate acceleration was observed with 2-PyMe2SiH in the Rh-catalyzed reaction, huge rate deceleration was observed with 2-PyMe2SiH and 4-PyMe2SiH in the Pt-catalyzed reaction.

Original languageEnglish
Pages (from-to)1088-1089
Number of pages2
JournalChemistry Letters
Issue number11
DOIs
Publication statusPublished - Jan 1 2001
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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