Unprecedented reversible redox process in the ZnMFI-H 2 system involving formation of stable atomic Zn 0

Akira Oda, Hiroe Torigoe, Atsushi Itadani, Takahiro Ohkubo, Takashi Yumura, Hisayoshi Kobayashi, Yasushige Kuroda

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

In its element: Zn 2+ at the M7 site of MFI-type zeolites activates H 2, via ZnH and OH species, and leads to Zn 0 species. The Zn 0 species returns to its original state, a Zn 2+ ion, upon evacuation of the zeolite at 873 K (see picture). The formation of the Zn 0 species is supported by DFT calculations.

Original languageEnglish
Pages (from-to)7719-7723
Number of pages5
JournalAngewandte Chemie - International Edition
Volume51
Issue number31
DOIs
Publication statusPublished - Jul 27 2012

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Zeolites
Discrete Fourier transforms
Ions
Oxidation-Reduction

Keywords

  • density functional calculations
  • hydrides
  • hydrogen activation
  • redox chemistry
  • zeolites

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Unprecedented reversible redox process in the ZnMFI-H 2 system involving formation of stable atomic Zn 0 . / Oda, Akira; Torigoe, Hiroe; Itadani, Atsushi; Ohkubo, Takahiro; Yumura, Takashi; Kobayashi, Hisayoshi; Kuroda, Yasushige.

In: Angewandte Chemie - International Edition, Vol. 51, No. 31, 27.07.2012, p. 7719-7723.

Research output: Contribution to journalArticle

Oda, Akira ; Torigoe, Hiroe ; Itadani, Atsushi ; Ohkubo, Takahiro ; Yumura, Takashi ; Kobayashi, Hisayoshi ; Kuroda, Yasushige. / Unprecedented reversible redox process in the ZnMFI-H 2 system involving formation of stable atomic Zn 0 . In: Angewandte Chemie - International Edition. 2012 ; Vol. 51, No. 31. pp. 7719-7723.
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