Ultraviolet photoemission study of lithium nickel oxide: A contact of valence-band structure and selective oxidation

T. Miyazaki; D. Yoshimura; K. Okudaira

doi:10.1016/j.apcata.2007.12.025

Ultraviolet photoemission study of lithium nickel oxide: A contact of valence-band structure and selective oxidation

T. Miyazaki, D. Yoshimura, K. Okudaira

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We present a study of ultraviolet photoemission spectroscopy (UPS) and constant-initial-state spectroscopy (CIS) of lithium nickel oxide using synchrotron radiation. The top valence-band structure of Li_0.1Ni_1.9O₂ and LiNiO₂ has been applied to the investigation of selectivity for oxidative coupling of methane. It is suggested that lattice oxygen species are separable into two bands, and the proportion of the two O2p and Ni3d states was related to the function of the selective oxidation.

Original language	English
Pages (from-to)	79-82
Number of pages	4
Journal	Applied Catalysis A: General
Volume	338
Issue number	1-2
DOIs	https://doi.org/10.1016/j.apcata.2007.12.025
Publication status	Published - Apr 1 2008
Externally published	Yes

Keywords

Lithium nickel oxides
Oxidative coupling of methane
Selective oxidation
Ultraviolet photoemission spectroscopy
Valence-band structure

ASJC Scopus subject areas

Catalysis
Process Chemistry and Technology

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10.1016/j.apcata.2007.12.025

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title = "Ultraviolet photoemission study of lithium nickel oxide: A contact of valence-band structure and selective oxidation",

abstract = "We present a study of ultraviolet photoemission spectroscopy (UPS) and constant-initial-state spectroscopy (CIS) of lithium nickel oxide using synchrotron radiation. The top valence-band structure of Li0.1Ni1.9O2 and LiNiO2 has been applied to the investigation of selectivity for oxidative coupling of methane. It is suggested that lattice oxygen species are separable into two bands, and the proportion of the two O2p and Ni3d states was related to the function of the selective oxidation.",

keywords = "Lithium nickel oxides, Oxidative coupling of methane, Selective oxidation, Ultraviolet photoemission spectroscopy, Valence-band structure",

author = "T. Miyazaki and D. Yoshimura and K. Okudaira",

year = "2008",

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doi = "10.1016/j.apcata.2007.12.025",

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TY - JOUR

T1 - Ultraviolet photoemission study of lithium nickel oxide

T2 - A contact of valence-band structure and selective oxidation

AU - Miyazaki, T.

AU - Yoshimura, D.

AU - Okudaira, K.

PY - 2008/4/1

Y1 - 2008/4/1

N2 - We present a study of ultraviolet photoemission spectroscopy (UPS) and constant-initial-state spectroscopy (CIS) of lithium nickel oxide using synchrotron radiation. The top valence-band structure of Li0.1Ni1.9O2 and LiNiO2 has been applied to the investigation of selectivity for oxidative coupling of methane. It is suggested that lattice oxygen species are separable into two bands, and the proportion of the two O2p and Ni3d states was related to the function of the selective oxidation.

AB - We present a study of ultraviolet photoemission spectroscopy (UPS) and constant-initial-state spectroscopy (CIS) of lithium nickel oxide using synchrotron radiation. The top valence-band structure of Li0.1Ni1.9O2 and LiNiO2 has been applied to the investigation of selectivity for oxidative coupling of methane. It is suggested that lattice oxygen species are separable into two bands, and the proportion of the two O2p and Ni3d states was related to the function of the selective oxidation.

KW - Lithium nickel oxides

KW - Oxidative coupling of methane

KW - Selective oxidation

KW - Ultraviolet photoemission spectroscopy

KW - Valence-band structure

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DO - 10.1016/j.apcata.2007.12.025

M3 - Article

AN - SCOPUS:40149094443

SN - 0926-860X

VL - 338

SP - 79

EP - 82

JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

IS - 1-2

ER -

Ultraviolet photoemission study of lithium nickel oxide: A contact of valence-band structure and selective oxidation

Abstract

Keywords

ASJC Scopus subject areas

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