Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama; Keiichi Adachi; Khayrul Kabir; Susumu Kitagawa; Takayoshi Suzuki; Sumio Kaizaki; Satoshi Kawata

Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama, Keiichi Adachi, Khayrul Kabir, Susumu Kitagawa, Takayoshi Suzuki, Sumio Kaizaki, Satoshi Kawata

Research output: Contribution to journal › Article › peer-review

Abstract

The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]₂[M(tdpd)₂(OH₂) ₂·2H₂O (M = Mn²⁺ (1), Zn²⁺ (2); Hrael⁺ = melaminium cation; H₂tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

Original language	English
Pages (from-to)	419-424
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	379
Publication status	Published - Dec 1 2002
Externally published	Yes

Keywords

Manganese
Triple hydrogen bonding
Zinc

ASJC Scopus subject areas

Condensed Matter Physics

Cite this

Sugiyama, Y., Adachi, K., Kabir, K., Kitagawa, S., Suzuki, T., Kaizaki, S., & Kawata, S. (2002). Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 379, 419-424.

Triple hydrogen bond directed crystal engineering of metal assembled complexes : The effect of a novel organic-inorganic module on supramolecular structure. / Sugiyama, Yuichi; Adachi, Keiichi; Kabir, Khayrul; Kitagawa, Susumu; Suzuki, Takayoshi; Kaizaki, Sumio; Kawata, Satoshi.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 379, 01.12.2002, p. 419-424.

Research output: Contribution to journal › Article › peer-review

Sugiyama, Y, Adachi, K, Kabir, K, Kitagawa, S, Suzuki, T, Kaizaki, S & Kawata, S 2002, 'Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 379, pp. 419-424.

Sugiyama, Yuichi ; Adachi, Keiichi ; Kabir, Khayrul ; Kitagawa, Susumu ; Suzuki, Takayoshi ; Kaizaki, Sumio ; Kawata, Satoshi. / Triple hydrogen bond directed crystal engineering of metal assembled complexes : The effect of a novel organic-inorganic module on supramolecular structure. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002 ; Vol. 379. pp. 419-424.

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AB - The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

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Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Abstract

Keywords

ASJC Scopus subject areas

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