Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama; Keiichi Adachi; Khayrul Kabir; Susumu Kitagawa; Takayoshi Suzuki; Sumio Kaizaki; Satoshi Kawata

Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama, Keiichi Adachi, Khayrul Kabir, Susumu Kitagawa, Takayoshi Suzuki, Sumio Kaizaki, Satoshi Kawata

Research output: Contribution to journal › Article › peer-review

Abstract

The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]₂[M(tdpd)₂(OH₂) ₂·2H₂O (M = Mn²⁺ (1), Zn²⁺ (2); Hrael⁺ = melaminium cation; H₂tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

Original language	English
Pages (from-to)	419-424
Number of pages	6
Journal	Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume	379
Publication status	Published - Dec 1 2002
Externally published	Yes

Keywords

Manganese
Triple hydrogen bonding
Zinc

ASJC Scopus subject areas

Condensed Matter Physics

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Sugiyama, Y., Adachi, K., Kabir, K., Kitagawa, S., Suzuki, T., Kaizaki, S., & Kawata, S. (2002). Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 379, 419-424.

Triple hydrogen bond directed crystal engineering of metal assembled complexes : The effect of a novel organic-inorganic module on supramolecular structure. / Sugiyama, Yuichi; Adachi, Keiichi; Kabir, Khayrul; Kitagawa, Susumu; Suzuki, Takayoshi; Kaizaki, Sumio; Kawata, Satoshi.

In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, Vol. 379, 01.12.2002, p. 419-424.

Research output: Contribution to journal › Article › peer-review

Sugiyama, Y, Adachi, K, Kabir, K, Kitagawa, S, Suzuki, T, Kaizaki, S & Kawata, S 2002, 'Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure', Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, vol. 379, pp. 419-424.

Sugiyama, Yuichi ; Adachi, Keiichi ; Kabir, Khayrul ; Kitagawa, Susumu ; Suzuki, Takayoshi ; Kaizaki, Sumio ; Kawata, Satoshi. / Triple hydrogen bond directed crystal engineering of metal assembled complexes : The effect of a novel organic-inorganic module on supramolecular structure. In: Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals. 2002 ; Vol. 379. pp. 419-424.

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AU - Kawata, Satoshi

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AB - The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

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Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Abstract

Keywords

ASJC Scopus subject areas

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