Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama, Keiichi Adachi, Khayrul Kabir, Susumu Kitagawa, Takayoshi Suzuki, Sumio Kaizaki, Satoshi Kawata

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

Original languageEnglish
Pages (from-to)419-424
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume379
Publication statusPublished - Dec 1 2002
Externally publishedYes

Keywords

  • Manganese
  • Triple hydrogen bonding
  • Zinc

ASJC Scopus subject areas

  • Condensed Matter Physics

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