Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure

Yuichi Sugiyama, Keiichi Adachi, Khayrul Kabir, Susumu Kitagawa, Takayoshi Suzuki, Sumio Kaizaki, Satoshi Kawata

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

Original languageEnglish
Pages (from-to)419-424
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume379
Publication statusPublished - 2002
Externally publishedYes

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Crystal engineering
Hydrogen
Hydrogen bonds
modules
Metals
engineering
hydrogen bonds
Dichlorodiphenyldichloroethane
hydrogen
Manganese
metals
crystals
Cations
manganese
Zinc
zinc
Crystal structure
Positive ions
Single crystals
cations

Keywords

  • Manganese
  • Triple hydrogen bonding
  • Zinc

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

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T1 - Triple hydrogen bond directed crystal engineering of metal assembled complexes

T2 - The effect of a novel organic-inorganic module on supramolecular structure

AU - Sugiyama, Yuichi

AU - Adachi, Keiichi

AU - Kabir, Khayrul

AU - Kitagawa, Susumu

AU - Suzuki, Takayoshi

AU - Kaizaki, Sumio

AU - Kawata, Satoshi

PY - 2002

Y1 - 2002

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AB - The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.

KW - Manganese

KW - Triple hydrogen bonding

KW - Zinc

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