Abstract
The new manganese(II) and zinc(II) triply hydrogen-bonded complexes [Hmel]2[M(tdpd)2(OH2) 2·2H2O (M = Mn2+ (1), Zn2+ (2); Hrael+ = melaminium cation; H2tdpd = 1,4,5,6-tetrahydro-5,6-dioxo2,3-pyrazinedicarbonitrile) have been synthesized and characterized. These complexes are isostructural as revealed by their single crystal structure analyses. Both the compounds are composed of triply hydrogen-bonded module of the AAA ≡ DDD system.
| Original language | English |
|---|---|
| Pages (from-to) | 419-424 |
| Number of pages | 6 |
| Journal | Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals |
| Volume | 379 |
| Publication status | Published - Dec 1 2002 |
| Externally published | Yes |
Keywords
- Manganese
- Triple hydrogen bonding
- Zinc
ASJC Scopus subject areas
- Condensed Matter Physics
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Sugiyama, Y., Adachi, K., Kabir, K., Kitagawa, S., Suzuki, T., Kaizaki, S., & Kawata, S. (2002). Triple hydrogen bond directed crystal engineering of metal assembled complexes: The effect of a novel organic-inorganic module on supramolecular structure. Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals, 379, 419-424.