Abstract
Preparation of trans-(Methanol)(methyldiphenyl-phosphine)bis(pentane-2,4-dionato)-cobalt(III) hexafluorophosphatehydrate is described. There is an intermolecular hydrogen bond between the OH group of the coordinated methanol and one of the O atoms of the acac ligands in an adjacent complex cation, [giving a centrosymmetric dimeric dicationic complex. This is, to my knowledge, the first X-ray crystallographic study of a non-organometallic cobalt(III) complex bearing a methanol ligand, although two organo?cobaloxime derivatives with a coordinated methanol ligand have been reported. The population of these disordered atoms were assumed to be 0.5. The O atom of water of crystallization was treated as two partial-occupancy isotropic O atoms. H atoms bound to the O atom were not included in the calculation. All other H atoms were included in the structural calculation by means of a riding model.
| Original language | English |
|---|---|
| Pages (from-to) | e118-e119 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 56 |
| Issue number | 4 |
| Publication status | Published - 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Biochemistry, Genetics and Molecular Biology(all)
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Trans-(Methanol)(methyldiphenyl- Phosphine)bis(pentane-2,4-dionato)-cobalt(III) hexafluorophosphate hydrate. / Suzuki, Takayoshi.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 4, 2000, p. e118-e119.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Trans-(Methanol)(methyldiphenyl- Phosphine)bis(pentane-2,4-dionato)-cobalt(III) hexafluorophosphate hydrate
AU - Suzuki, Takayoshi
PY - 2000
Y1 - 2000
N2 - Preparation of trans-(Methanol)(methyldiphenyl-phosphine)bis(pentane-2,4-dionato)-cobalt(III) hexafluorophosphatehydrate is described. There is an intermolecular hydrogen bond between the OH group of the coordinated methanol and one of the O atoms of the acac ligands in an adjacent complex cation, [giving a centrosymmetric dimeric dicationic complex. This is, to my knowledge, the first X-ray crystallographic study of a non-organometallic cobalt(III) complex bearing a methanol ligand, although two organo?cobaloxime derivatives with a coordinated methanol ligand have been reported. The population of these disordered atoms were assumed to be 0.5. The O atom of water of crystallization was treated as two partial-occupancy isotropic O atoms. H atoms bound to the O atom were not included in the calculation. All other H atoms were included in the structural calculation by means of a riding model.
AB - Preparation of trans-(Methanol)(methyldiphenyl-phosphine)bis(pentane-2,4-dionato)-cobalt(III) hexafluorophosphatehydrate is described. There is an intermolecular hydrogen bond between the OH group of the coordinated methanol and one of the O atoms of the acac ligands in an adjacent complex cation, [giving a centrosymmetric dimeric dicationic complex. This is, to my knowledge, the first X-ray crystallographic study of a non-organometallic cobalt(III) complex bearing a methanol ligand, although two organo?cobaloxime derivatives with a coordinated methanol ligand have been reported. The population of these disordered atoms were assumed to be 0.5. The O atom of water of crystallization was treated as two partial-occupancy isotropic O atoms. H atoms bound to the O atom were not included in the calculation. All other H atoms were included in the structural calculation by means of a riding model.
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UR - http://www.scopus.com/inward/citedby.url?scp=84924959620&partnerID=8YFLogxK
M3 - Article
VL - 56
SP - e118-e119
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 4
ER -