Trans-Bis(O-ethylxanthato)bis(triphenylphosphine)ruthenium(III) hexafluorophosphate monohydrate

Yuko Ohuchi, Kyoko Noda, Takayoshi Suzuki, Kazuo Kashiwabara, Hideo D. Takagi

Research output: Contribution to journalArticle

Abstract

In the monoclinic crystal structure of the title compound, trans-[Ru(C 3H5OS2)2(C18H 15P)2]PF6·H2O, the structure of the RuIII complex cation is very similar to that in the orthorhombic crystal of the nonhydrated complex [Noda, Ohuchi, Hashimoto, Fujiki, Itoh, Iwatsuki, Noda, Suzuki, Kashiwabara & Takagi (2006), Inorg. Chem.45, 1349-1355]. In the present crystal structure, the P - Ru - P bond axes of the complex cations are aligned parallel to the [101] direction.

Original languageEnglish
JournalActa Crystallographica Section E: Structure Reports Online
Volume62
Issue number5
DOIs
Publication statusPublished - May 2006
Externally publishedYes

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Ruthenium
ruthenium
Cations
Crystal structure
Positive ions
cations
crystal structure
Crystals
crystals
triphenylphosphine
Direction compound
dichlorotetrakis(dimethyl sulfoxide)ruthenium II

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

Trans-Bis(O-ethylxanthato)bis(triphenylphosphine)ruthenium(III) hexafluorophosphate monohydrate. / Ohuchi, Yuko; Noda, Kyoko; Suzuki, Takayoshi; Kashiwabara, Kazuo; Takagi, Hideo D.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 62, No. 5, 05.2006.

Research output: Contribution to journalArticle

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AU - Kashiwabara, Kazuo

AU - Takagi, Hideo D.

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