Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

Takayoshi Suzuki; Masahiro Ogita; Sumio Kaizaki

Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N ⁴)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

Takayoshi Suzuki, Masahiro Ogita, Sumio Kaizaki

Research output: Contribution to journal › Article › peer-review

Abstract

The complex cation in the title compound, [Co(C₅H₇O₂)₂-(C₉H ₂₀N₂)(C₁₈H₁₅P)]PF ₆·CH₂Cl₂, is the first example of a Co^III complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh₃ ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh₃ ligands.

Original language	English
Pages (from-to)	532-533
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	56
Issue number	5
Publication status	Published - May 1 2000
Externally published	Yes

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N ⁴)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate. / Suzuki, Takayoshi; Ogita, Masahiro; Kaizaki, Sumio.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 5, 01.05.2000, p. 532-533.

Research output: Contribution to journal › Article › peer-review

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title = "Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate",

abstract = "The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.",

author = "Takayoshi Suzuki and Masahiro Ogita and Sumio Kaizaki",

year = "2000",

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language = "English",

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pages = "532--533",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

AU - Suzuki, Takayoshi

AU - Ogita, Masahiro

AU - Kaizaki, Sumio

PY - 2000/5/1

Y1 - 2000/5/1

N2 - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

AB - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

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VL - 56

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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