Abstract
The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.
| Original language | English |
|---|---|
| Pages (from-to) | 532-533 |
| Number of pages | 2 |
| Journal | Acta Crystallographica Section C: Crystal Structure Communications |
| Volume | 56 |
| Issue number | 5 |
| Publication status | Published - May 2000 |
| Externally published | Yes |
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ASJC Scopus subject areas
- Condensed Matter Physics
- Structural Biology
Cite this
Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate. / Suzuki, Takayoshi; Ogita, Masahiro; Kaizaki, Sumio.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 56, No. 5, 05.2000, p. 532-533.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate
AU - Suzuki, Takayoshi
AU - Ogita, Masahiro
AU - Kaizaki, Sumio
PY - 2000/5
Y1 - 2000/5
N2 - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.
AB - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.
UR - http://www.scopus.com/inward/record.url?scp=0000559927&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0000559927&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0000559927
VL - 56
SP - 532
EP - 533
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
SN - 0108-2701
IS - 5
ER -