Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

Takayoshi Suzuki, Masahiro Ogita, Sumio Kaizaki

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

Original languageEnglish
Pages (from-to)532-533
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number5
Publication statusPublished - May 1 2000
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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