Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

Takayoshi Suzuki, Masahiro Ogita, Sumio Kaizaki

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

Original languageEnglish
Pages (from-to)532-533
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume56
Issue number5
Publication statusPublished - May 2000
Externally publishedYes

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Methylene Chloride
pentanes
Cobalt
cobalt
Ligands
ligands
phosphine
X ray analysis
phosphines
Amines
Cations
amines
X-Rays
cations
triphenylphosphine
4-amino-2,2,6,6-tetramethylpiperidine
pentane
configurations
x rays
interactions

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Structural Biology

Cite this

@article{54a455ed92224955a914725d50972576,
title = "Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate",
abstract = "The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.",
author = "Takayoshi Suzuki and Masahiro Ogita and Sumio Kaizaki",
year = "2000",
month = "5",
language = "English",
volume = "56",
pages = "532--533",
journal = "Acta Crystallographica Section C: Crystal Structure Communications",
issn = "0108-2701",
publisher = "International Union of Crystallography",
number = "5",

}

TY - JOUR

T1 - Trans-(4-Amino-2,2,6,6-tetramethylpiperidine-N 4)bis(pentane-2,4-dionato-O,O′)(triphenylphosphine-P)- cobalt(III) hexafluorophosphate dichloromethane solvate

AU - Suzuki, Takayoshi

AU - Ogita, Masahiro

AU - Kaizaki, Sumio

PY - 2000/5

Y1 - 2000/5

N2 - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

AB - The complex cation in the title compound, [Co(C5H7O2)2-(C9H 20N2)(C18H15P)]PF 6·CH2Cl2, is the first example of a CoIII complex in which a trans configuration for the coordinated monodentate phosphine and amine ligands has been confirmed by X-ray analysis. Owing to the large steric bulkiness of the axial PPh3 ligands influencing the interaction with the equatorial acetylacetonate ligands, the acetylacetonate planes bend away considerably from the PPh3 ligands.

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M3 - Article

VL - 56

SP - 532

EP - 533

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

SN - 0108-2701

IS - 5

ER -