A novel route to (±)-platencin is reported, in which the highly stereoselective alkylative quaternization of a cyclohexenone scaffold via 1,4-diastereoinduction and two radical carbon-carbon bond-forming reactions that involve titanium(III)-mediated cyclization and stannyl-radical-mediated skeletal rearrangement are utilized.
|Number of pages||4|
|Publication status||Published - Jul 15 2011|
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry