Total synthesis of (±)-platencin

Takehiko Yoshimitsu, Shoji Nojima, Masashi Hashimoto, Tetsuaki Tanaka

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

A novel route to (±)-platencin is reported, in which the highly stereoselective alkylative quaternization of a cyclohexenone scaffold via 1,4-diastereoinduction and two radical carbon-carbon bond-forming reactions that involve titanium(III)-mediated cyclization and stannyl-radical-mediated skeletal rearrangement are utilized.

Original languageEnglish
Pages (from-to)3698-3701
Number of pages4
JournalOrganic Letters
Volume13
Issue number14
DOIs
Publication statusPublished - Jul 15 2011
Externally publishedYes

    Fingerprint

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

Cite this

Yoshimitsu, T., Nojima, S., Hashimoto, M., & Tanaka, T. (2011). Total synthesis of (±)-platencin. Organic Letters, 13(14), 3698-3701. https://doi.org/10.1021/ol2013439