Ti-O hybridization effect on ferroelectric phase transition of BaTiO3

Tohru Higuchi; Takeyo Tsukamoto; Kunihiko Oka; Takayoshi Yokoya; Yasuhisa Tezuka; Shik Shin

Ti-O hybridization effect on ferroelectric phase transition of BaTiO₃

Tohru Higuchi, Takeyo Tsukamoto, Kunihiko Oka, Takayoshi Yokoya, Yasuhisa Tezuka, Shik Shin

Research output: Contribution to journal › Article › peer-review

Abstract

The Ti-O hybridization effect on the ferroelectric phase transition of BaTiO₃ has been studied by resonant-photoemission spectroscopy. The Ti 3d partial-density-of-state in the valence band of the paraelectric phase is larger than that of the ferroelectric phase. This fact indicates that the Ti-O hybridization effect is stronger in the paraelectric phase.

Original language	English
Pages (from-to)	5667-5669
Number of pages	3
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	38
Issue number	9 B
Publication status	Published - Dec 1 1999
Externally published	Yes

Keywords

BaTiO
Ferroelectric phase
Paraelectric phase
Resonant-photoemission
Ti-O hybridization

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

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Ti-O hybridization effect on ferroelectric phase transition of BaTiO₃. / Higuchi, Tohru; Tsukamoto, Takeyo; Oka, Kunihiko; Yokoya, Takayoshi; Tezuka, Yasuhisa; Shin, Shik.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 38, No. 9 B, 01.12.1999, p. 5667-5669.

Research output: Contribution to journal › Article › peer-review

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AU - Tsukamoto, Takeyo

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AU - Tezuka, Yasuhisa

AU - Shin, Shik

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N2 - The Ti-O hybridization effect on the ferroelectric phase transition of BaTiO3 has been studied by resonant-photoemission spectroscopy. The Ti 3d partial-density-of-state in the valence band of the paraelectric phase is larger than that of the ferroelectric phase. This fact indicates that the Ti-O hybridization effect is stronger in the paraelectric phase.

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KW - Paraelectric phase

KW - Resonant-photoemission

KW - Ti-O hybridization

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