Thyminate(2-)-bridged cyclic tetranuclear rhodium(III) complexes formed by a template of a sodium, calcium or lanthanoid ion

Ayana Kashima, Mika Sakate, Hiromi Ota, Akira Fuyuhiro, Yukinari Sunatsuki, Takayoshi Suzuki

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

In the thyminate(2-)-bridged tetranuclear Cp∗RhIII complexes incorporating a Na+, Ca2+ or Ln3+ cation, homochiral aggregation of four RhIII centres was achieved to form metallacalix[4]arene-type clusters. The thyminate(2-) bridged two RhIII and the third metal ion with a μ3-1κN1:2κ2N3,O2:3κO2 mode in the Na+ and Ca2+ complexes, while in the Ln3+ analogues it exhibited a different bridging mode, μ3-1κN1:2κ2N3,O4:3κO2.

Original languageEnglish
Pages (from-to)1889-1892
Number of pages4
JournalChemical Communications
Volume51
Issue number10
DOIs
Publication statusPublished - Feb 4 2015

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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