Thermoelectric property of polycrystalline aluminum-doped zinc oxide enhanced by micropore foaming

Takasi Teranisi, Yosuke Mori, Hidetaka Hayashi, Akira Kishimoto

Research output: Contribution to journalArticle

10 Citations (Scopus)

Abstract

A unique micropore foaming technique was used to enhance the thermoelectric properties of polycrystalline aluminum-doped zinc oxide (AZO). Silicon carbide (α-SiC) and aluminum nitride (AlN) were used as foaming precursors. Thermoelectric conductivity, I, decreased on addition of both precursors, increasing the porosity. Electric conductivity, Ï, decreased upon addition of α-SiC, and subsequent addition of AlN reversed the effect. This phenomenon is due to the chemical reactions that occur upon addition of each precursor: the active oxidation of α-SiC and the decomposition reaction of AlN. The Seebeck coefficient, S, for 0.5 mol% AlN-doped AZO (Al 0.005Zn 0.995O, AZO-0.005) was more than twice that of conventional non-doped AZO. Accordingly, the power factor and the figure of merit, ZT, for the porous AlN-doped AZO-0.005 were 4.9 and 5.8 times those of the conventional polycrystalline AZO, respectively, demonstrating that the compositionally optimized porous AZO exhibited excellent thermoelectric properties at high temperatures.

Original languageEnglish
Pages (from-to)690-695
Number of pages6
JournalJournal of the American Ceramic Society
Volume95
Issue number2
DOIs
Publication statusPublished - Feb 2012

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Zinc Oxide
Zinc oxide
Aluminum
Aluminum nitride
Seebeck coefficient
Electric conductivity
Silicon carbide
Chemical reactions
Porosity
aluminum nitride
Decomposition
Oxidation

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Thermoelectric property of polycrystalline aluminum-doped zinc oxide enhanced by micropore foaming. / Teranisi, Takasi; Mori, Yosuke; Hayashi, Hidetaka; Kishimoto, Akira.

In: Journal of the American Ceramic Society, Vol. 95, No. 2, 02.2012, p. 690-695.

Research output: Contribution to journalArticle

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abstract = "A unique micropore foaming technique was used to enhance the thermoelectric properties of polycrystalline aluminum-doped zinc oxide (AZO). Silicon carbide (α-SiC) and aluminum nitride (AlN) were used as foaming precursors. Thermoelectric conductivity, I, decreased on addition of both precursors, increasing the porosity. Electric conductivity, {\"I}, decreased upon addition of α-SiC, and subsequent addition of AlN reversed the effect. This phenomenon is due to the chemical reactions that occur upon addition of each precursor: the active oxidation of α-SiC and the decomposition reaction of AlN. The Seebeck coefficient, S, for 0.5 mol{\%} AlN-doped AZO (Al 0.005Zn 0.995O, AZO-0.005) was more than twice that of conventional non-doped AZO. Accordingly, the power factor and the figure of merit, ZT, for the porous AlN-doped AZO-0.005 were 4.9 and 5.8 times those of the conventional polycrystalline AZO, respectively, demonstrating that the compositionally optimized porous AZO exhibited excellent thermoelectric properties at high temperatures.",
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