Abstract
In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.
Original language | English |
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Pages (from-to) | 391-395 |
Number of pages | 5 |
Journal | CrystEngComm |
Volume | 13 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jan 21 2011 |
Externally published | Yes |
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics