Abstract
In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.
| Original language | English |
|---|---|
| Pages (from-to) | 391-395 |
| Number of pages | 5 |
| Journal | CrystEngComm |
| Volume | 13 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jan 21 2011 |
| Externally published | Yes |
Fingerprint
ASJC Scopus subject areas
- Chemistry(all)
- Materials Science(all)
- Condensed Matter Physics
Cite this
Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer. / Phan, Ngoc Hien; Halasz, Ivan; Opahle, Ingo; Alig, Edith; Fink, Lothar; Bats, Jan W.; Cong, Pham Thanh; Lerner, Hans Wolfram; Sarkar, Biprajit; Wolf, Bernd; Jeschke, Harald Olaf; Lang, Michael; Valentí, Roser; Dinnebier, Robert; Wagner, Matthias.
In: CrystEngComm, Vol. 13, No. 2, 21.01.2011, p. 391-395.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer
AU - Phan, Ngoc Hien
AU - Halasz, Ivan
AU - Opahle, Ingo
AU - Alig, Edith
AU - Fink, Lothar
AU - Bats, Jan W.
AU - Cong, Pham Thanh
AU - Lerner, Hans Wolfram
AU - Sarkar, Biprajit
AU - Wolf, Bernd
AU - Jeschke, Harald Olaf
AU - Lang, Michael
AU - Valentí, Roser
AU - Dinnebier, Robert
AU - Wagner, Matthias
PY - 2011/1/21
Y1 - 2011/1/21
N2 - In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.
AB - In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.
UR - http://www.scopus.com/inward/record.url?scp=78650402449&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=78650402449&partnerID=8YFLogxK
U2 - 10.1039/c0ce00367k
DO - 10.1039/c0ce00367k
M3 - Article
AN - SCOPUS:78650402449
VL - 13
SP - 391
EP - 395
JO - CrystEngComm
JF - CrystEngComm
SN - 1466-8033
IS - 2
ER -