Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer

Ngoc Hien Phan, Ivan Halasz, Ingo Opahle, Edith Alig, Lothar Fink, Jan W. Bats, Pham Thanh Cong, Hans Wolfram Lerner, Biprajit Sarkar, Bernd Wolf, Harald Olaf Jeschke, Michael Lang, Roser Valentí, Robert Dinnebier, Matthias Wagner

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.

Original languageEnglish
Pages (from-to)391-395
Number of pages5
JournalCrystEngComm
Volume13
Issue number2
DOIs
Publication statusPublished - Jan 21 2011
Externally publishedYes

Fingerprint

Exchange coupling
coordination polymers
oxygen atoms
Magnetic properties
Polymers
Ligands
Oxygen
magnetic properties
Heating
Atoms
Crystals
ligands
heating
polymers
products
crystals
interactions

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer. / Phan, Ngoc Hien; Halasz, Ivan; Opahle, Ingo; Alig, Edith; Fink, Lothar; Bats, Jan W.; Cong, Pham Thanh; Lerner, Hans Wolfram; Sarkar, Biprajit; Wolf, Bernd; Jeschke, Harald Olaf; Lang, Michael; Valentí, Roser; Dinnebier, Robert; Wagner, Matthias.

In: CrystEngComm, Vol. 13, No. 2, 21.01.2011, p. 391-395.

Research output: Contribution to journalArticle

Phan, NH, Halasz, I, Opahle, I, Alig, E, Fink, L, Bats, JW, Cong, PT, Lerner, HW, Sarkar, B, Wolf, B, Jeschke, HO, Lang, M, Valentí, R, Dinnebier, R & Wagner, M 2011, 'Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer', CrystEngComm, vol. 13, no. 2, pp. 391-395. https://doi.org/10.1039/c0ce00367k
Phan, Ngoc Hien ; Halasz, Ivan ; Opahle, Ingo ; Alig, Edith ; Fink, Lothar ; Bats, Jan W. ; Cong, Pham Thanh ; Lerner, Hans Wolfram ; Sarkar, Biprajit ; Wolf, Bernd ; Jeschke, Harald Olaf ; Lang, Michael ; Valentí, Roser ; Dinnebier, Robert ; Wagner, Matthias. / Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer. In: CrystEngComm. 2011 ; Vol. 13, No. 2. pp. 391-395.
@article{2813c8e43a7749dd9c198bf75b6471ea,
title = "Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer",
abstract = "In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.",
author = "Phan, {Ngoc Hien} and Ivan Halasz and Ingo Opahle and Edith Alig and Lothar Fink and Bats, {Jan W.} and Cong, {Pham Thanh} and Lerner, {Hans Wolfram} and Biprajit Sarkar and Bernd Wolf and Jeschke, {Harald Olaf} and Michael Lang and Roser Valent{\'i} and Robert Dinnebier and Matthias Wagner",
year = "2011",
month = "1",
day = "21",
doi = "10.1039/c0ce00367k",
language = "English",
volume = "13",
pages = "391--395",
journal = "CrystEngComm",
issn = "1466-8033",
publisher = "Royal Society of Chemistry",
number = "2",

}

TY - JOUR

T1 - Thermally induced crystal-to-crystal transformations accompanied by changes in the magnetic properties of a CuII-p-hydroquinonate polymer

AU - Phan, Ngoc Hien

AU - Halasz, Ivan

AU - Opahle, Ingo

AU - Alig, Edith

AU - Fink, Lothar

AU - Bats, Jan W.

AU - Cong, Pham Thanh

AU - Lerner, Hans Wolfram

AU - Sarkar, Biprajit

AU - Wolf, Bernd

AU - Jeschke, Harald Olaf

AU - Lang, Michael

AU - Valentí, Roser

AU - Dinnebier, Robert

AU - Wagner, Matthias

PY - 2011/1/21

Y1 - 2011/1/21

N2 - In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.

AB - In the CuII-p-hydroquinonate coordination polymer 1, the major pathway for antiferromagnetic exchange coupling runs along the hydroquinonate linker. Upon heating, 1 looses its supporting DMF ligands in a two-step sequence; the antiferromagnetic CuII-CuII interaction in the final product 3 is now mediated by two bridging oxygen atoms which results in an increase of the J value by two orders of magnitude.

UR - http://www.scopus.com/inward/record.url?scp=78650402449&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=78650402449&partnerID=8YFLogxK

U2 - 10.1039/c0ce00367k

DO - 10.1039/c0ce00367k

M3 - Article

AN - SCOPUS:78650402449

VL - 13

SP - 391

EP - 395

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

IS - 2

ER -