Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)6] (M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

Tomoyuki Tajima, Takayo Sasaki, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh

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Abstract

Thermal reactions of an overcrowded germacyclopropabenzene with hexacarbonyl complexes of group 6 metals resulted in the formation of the corresponding cyclic germoxycarbene complexes, i.e., 1,2-oxagermolan-5-ylidene pentacarbonyl metal complexes, via a novel mode of CO insertion reaction toward cyclopropabenzene derivatives.

Original languageEnglish
Pages (from-to)402-403
Number of pages2
JournalChemical Communications
Volume10
Issue number4
Publication statusPublished - Feb 21 2004
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

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