Thermal reactions of an overcrowded germacyclopropabenzene with group 6 metal hexacarbonyl complexes [M(CO)6](M = Cr, Mo, and W): A novel mode of CO insertion leading to the formation of cyclic germoxycarbene metal complexes

Tomoyuki Tajima, Takayo Sasaki, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Thermal reactions of an overcrowded germacyclopropabenzene with hexacarbonyl complexes of group 6 metals resulted in the formation of the corresponding cyclic germoxycarbene complexes, i.e., 1,2-oxagermolan-5-ylidene pentacarbonyl metal complexes, via a novel mode of CO insertion reaction toward cyclopropabenzene derivatives.

Original languageEnglish
Pages (from-to)402-403
Number of pages2
JournalChemical Communications
Volume4
Issue number4
DOIs
Publication statusPublished - Jan 1 2004
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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