Thermal properties and structures of chlorocadmate, bromocadmate, and bromochlorocadmate glasses

Shinichi Sakida, Hironobu Nakata, Yoji Kawamoto

Research output: Contribution to journalArticle

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Abstract

Glass transition temperatures (Tg), crystallization temperatures (Tx), and 113Cd magic-angle spinning (MAS) NMR spectra of the chlorocadmate, bromocadmate, and bromochlorocadmate glasses and the CdCl2, CdBrCl, and CdBr2 crystals have been measured. The Tg and Tx, and thermal stabilities (Tx - Tg) decreased with increasing Br-content. No enhancement of (Tx - Tg) of bromochlorocadmate glasses by anion-mixing was observed. The CdCl2 and CdBr2 crystals gave the isotropic chemical shifts of 183 and - 24 ppm, which are assigned to the CdCl6 and CdBr6 octahedra, respectively. The isotropic chemical shifts of CdBrCl crystal (186, 166, 135, 101, 63, 25 and - 21 ppm) were assigned to CdBrnCl(6-n) (n = 0-6) octahedra, respectively. It was found that the Br and Cl atoms in CdBrCl randomly occupy chlorine sites in the CdCl2 structure. The 113Cd MAS NMR spectra revealed that the chlorocadmate, bromocadmate, and bromochlorocadmate glasses are composed of the CdCl6, CdBr6 and CdBrnCl(6-n) octahedra (n = 0-6), respectively, and that the Cd2+ in all the bromochlorocadmate glasses was more preferentially bonded to Br- than Cl-. The relationship between the thermal properties and the anion coordination environments around Cd2+ in these glasses is discussed.

Original languageEnglish
Pages (from-to)447-452
Number of pages6
JournalSolid State Communications
Volume127
Issue number6
DOIs
Publication statusPublished - Aug 2003

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Thermodynamic properties
Cadmium Chloride
thermodynamic properties
Glass
glass
Magic angle spinning
Chemical shift
metal spinning
Crystals
Anions
chemical equilibrium
Negative ions
Nuclear magnetic resonance
anions
crystals
nuclear magnetic resonance
Chlorine
Crystallization
glass transition temperature
chlorine

Keywords

  • A. Disordered systems
  • E. Nuclear resonances

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Thermal properties and structures of chlorocadmate, bromocadmate, and bromochlorocadmate glasses. / Sakida, Shinichi; Nakata, Hironobu; Kawamoto, Yoji.

In: Solid State Communications, Vol. 127, No. 6, 08.2003, p. 447-452.

Research output: Contribution to journalArticle

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