Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

Yukinari Sunatsuki, Masafumi Sakata, Susumu Matsuzaki, Naohide Matsumoto, Masaaki Kojima

Research output: Contribution to journalArticle

44 Citations (Scopus)

Abstract

A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

Original languageEnglish
Pages (from-to)1254-1255
Number of pages2
JournalChemistry Letters
Issue number12
Publication statusPublished - 2001
Externally publishedYes

Fingerprint

Amines
Iron
Crystal structure
Ligands
Hot Temperature
imidazole

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups. / Sunatsuki, Yukinari; Sakata, Masafumi; Matsuzaki, Susumu; Matsumoto, Naohide; Kojima, Masaaki.

In: Chemistry Letters, No. 12, 2001, p. 1254-1255.

Research output: Contribution to journalArticle

Sunatsuki, Yukinari ; Sakata, Masafumi ; Matsuzaki, Susumu ; Matsumoto, Naohide ; Kojima, Masaaki. / Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups. In: Chemistry Letters. 2001 ; No. 12. pp. 1254-1255.
@article{a316b148a8664b6a921457ed63126321,
title = "Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups",
abstract = "A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.",
author = "Yukinari Sunatsuki and Masafumi Sakata and Susumu Matsuzaki and Naohide Matsumoto and Masaaki Kojima",
year = "2001",
language = "English",
pages = "1254--1255",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "12",

}

TY - JOUR

T1 - Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

AU - Sunatsuki, Yukinari

AU - Sakata, Masafumi

AU - Matsuzaki, Susumu

AU - Matsumoto, Naohide

AU - Kojima, Masaaki

PY - 2001

Y1 - 2001

N2 - A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

AB - A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

UR - http://www.scopus.com/inward/record.url?scp=0035528532&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0035528532&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0035528532

SP - 1254

EP - 1255

JO - Chemistry Letters

JF - Chemistry Letters

SN - 0366-7022

IS - 12

ER -