Thermal and pressure induced spin crossover of a novel iron(III) complex with a tripodal ligand involving three imidazole groups

Yukinari Sunatsuki, Masafumi Sakata, Susumu Matsuzaki, Naohide Matsumoto, Masaaki Kojima

Research output: Contribution to journalArticle

46 Citations (Scopus)

Abstract

A novel spin crossover Fe(III) complex, [Fe(H3L)](CIO4),·(4-fim)·H2O (H3L = tris[2-(((imidazol-4-yl)methylene)amino)-ethyl]amine, 4-fim = 4-formylimidazole), was synthesized and the crystal structure was determined at 293 K. Cryomagnetic measurements revealed a two-step spin conversion and a pressure induced spin crossover was observed.

Original languageEnglish
Pages (from-to)1254-1255
Number of pages2
JournalChemistry Letters
Issue number12
DOIs
Publication statusPublished - Jan 1 2001
Externally publishedYes

ASJC Scopus subject areas

  • Chemistry(all)

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