Theory of 3d Core Photoemission Spectra in Rare Earth Oxides Series

Tatsuroh Ikeda, Kozo Okada, Haruhiko Ogasawara, Akio Kotani

Research output: Contribution to journalArticle

32 Citations (Scopus)

Abstract

Systematic analysis is carried out for 3d core photoemission spectra of rare earth oxides R2O3 (R=La~Yb) and RO2 (R=Ce, Pr, Tb) with the use of the impurity Anderson model. From the comparison of the calculated and experimeutal spectra, we estimate the values of some key parameters such as the charge transfer energy, the strength of the hybridization interaction, etc. We propose a possible mechanism of a satellite in the spectra for Eu2O3 and Yb2O3, which is different from that for La2O3~Nd2O3. We also point out the reason why the RO2 structure is stable only for R=Ce, Pr and Tb.

Original languageEnglish
Pages (from-to)622-630
Number of pages9
Journaljournal of the physical society of japan
Volume59
Issue number2
DOIs
Publication statusPublished - Jan 1 1990
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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