Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond

Sobi Asako; Laurean Ilies; Pritha Verma; Saki Ichikawa; Eiichi Nakamura

doi:10.1246/cl.131205

Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond

Sobi Asako, Laurean Ilies, Pritha Verma, Saki Ichikawa, Eiichi Nakamura

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

A theoretical study on a tripodal alkoxydiphosphine (POP) ligand, which accelerates the nickel-catalyzed monosubstitution of a polyfluoroarene with an organozinc reagent, revealed that the alkoxy group and the diphosphine act independently to facilitate cooperation of a Lewis acid and a transition metal.

Original language	English
Pages (from-to)	726-728
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	5
DOIs	https://doi.org/10.1246/cl.131205
Publication status	Published - 2014
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1246/cl.131205

Cite this

@article{2365017409f34ae0bb639377b6738d20,

title = "Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond",

abstract = "A theoretical study on a tripodal alkoxydiphosphine (POP) ligand, which accelerates the nickel-catalyzed monosubstitution of a polyfluoroarene with an organozinc reagent, revealed that the alkoxy group and the diphosphine act independently to facilitate cooperation of a Lewis acid and a transition metal.",

author = "Sobi Asako and Laurean Ilies and Pritha Verma and Saki Ichikawa and Eiichi Nakamura",

year = "2014",

doi = "10.1246/cl.131205",

language = "English",

volume = "43",

pages = "726--728",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "Chemical Society of Japan",

number = "5",

}

TY - JOUR

T1 - Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond

AU - Asako, Sobi

AU - Ilies, Laurean

AU - Verma, Pritha

AU - Ichikawa, Saki

AU - Nakamura, Eiichi

PY - 2014

Y1 - 2014

N2 - A theoretical study on a tripodal alkoxydiphosphine (POP) ligand, which accelerates the nickel-catalyzed monosubstitution of a polyfluoroarene with an organozinc reagent, revealed that the alkoxy group and the diphosphine act independently to facilitate cooperation of a Lewis acid and a transition metal.

AB - A theoretical study on a tripodal alkoxydiphosphine (POP) ligand, which accelerates the nickel-catalyzed monosubstitution of a polyfluoroarene with an organozinc reagent, revealed that the alkoxy group and the diphosphine act independently to facilitate cooperation of a Lewis acid and a transition metal.

UR - http://www.scopus.com/inward/record.url?scp=84899808036&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84899808036&partnerID=8YFLogxK

U2 - 10.1246/cl.131205

DO - 10.1246/cl.131205

M3 - Article

AN - SCOPUS:84899808036

SN - 0366-7022

VL - 43

SP - 726

EP - 728

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this