Theoretical study on alkoxydiphosphine ligand for bimetallic cooperation in nickel-catalyzed monosubstitution of CF bond

Sobi Asako, Laurean Ilies, Pritha Verma, Saki Ichikawa, Eiichi Nakamura

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4 Citations (Scopus)

Abstract

A theoretical study on a tripodal alkoxydiphosphine (POP) ligand, which accelerates the nickel-catalyzed monosubstitution of a polyfluoroarene with an organozinc reagent, revealed that the alkoxy group and the diphosphine act independently to facilitate cooperation of a Lewis acid and a transition metal.

Original languageEnglish
Pages (from-to)726-728
Number of pages3
JournalChemistry Letters
Volume43
Issue number5
DOIs
Publication statusPublished - 2014

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ASJC Scopus subject areas

  • Chemistry(all)

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