The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles

Kazuma Gotoh, Koji Kawabata, Eiji Fujii, Kunimitsu Morishige, Taro Kinumoto, Yuki Miyazaki, Hiroyuki Ishida

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

Mesoporous carbon having platinum, ruthenium or palladium nanoparticles on exfoliated graphene sheets were produced from graphite oxide (GO) and metal complexes. The Pt included carbon was made by heating of the intercalation compound including tetraammineplatinum (II) chloride monohydrate. Samples having Ru or Pd are producible by heating in nitrogen gas atmosphere using hexaammineruthenium (III) chloride or tetraamminepalladium (II) chloride monohydrate instead of Pt complex. The particle sizes of platinum, ruthenium, and palladium were, respectively, 1-3, 1-2, and 3-7 nm. The platinum- or palladium-containing sample showed catalytic activity for oxygen reduction.

Original languageEnglish
Pages (from-to)2120-2124
Number of pages5
JournalCarbon
Volume47
Issue number8
DOIs
Publication statusPublished - Jul 2009

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Palladium
Platinum
Oxides
Ruthenium
Carbon
Nanoparticles
Chlorides
Heating
Intercalation compounds
Coordination Complexes
Metal complexes
Graphene
Catalyst activity
Nitrogen
Gases
Particle size
Oxygen

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles. / Gotoh, Kazuma; Kawabata, Koji; Fujii, Eiji; Morishige, Kunimitsu; Kinumoto, Taro; Miyazaki, Yuki; Ishida, Hiroyuki.

In: Carbon, Vol. 47, No. 8, 07.2009, p. 2120-2124.

Research output: Contribution to journalArticle

Gotoh, Kazuma ; Kawabata, Koji ; Fujii, Eiji ; Morishige, Kunimitsu ; Kinumoto, Taro ; Miyazaki, Yuki ; Ishida, Hiroyuki. / The use of graphite oxide to produce mesoporous carbon supporting Pt, Ru, or Pd nanoparticles. In: Carbon. 2009 ; Vol. 47, No. 8. pp. 2120-2124.
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