The Suzuki-Miyaura Coupling of Nitroarenes

M. Ramu Yadav; Masahiro Nagaoka; Myuto Kashihara; Rong Lin Zhong; Takanori Miyazaki; Shigeyoshi Sakaki; Yoshiaki Nakao

doi:10.1021/jacs.7b03159

The Suzuki-Miyaura Coupling of Nitroarenes

M. Ramu Yadav, Masahiro Nagaoka, Myuto Kashihara, Rong Lin Zhong, Takanori Miyazaki, Shigeyoshi Sakaki, Yoshiaki Nakao

Research output: Contribution to journal › Article › peer-review

136 Citations (Scopus)

Abstract

Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO₂) bond by palladium, which represents an unprecedented elemental reaction.

Original language	English
Pages (from-to)	9423-9426
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	139
Issue number	28
DOIs	https://doi.org/10.1021/jacs.7b03159
Publication status	Published - Jul 19 2017
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/jacs.7b03159

Cite this

@article{0542bb5828224722ada6b8a205995891,

title = "The Suzuki-Miyaura Coupling of Nitroarenes",

abstract = "Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.",

author = "Yadav, {M. Ramu} and Masahiro Nagaoka and Myuto Kashihara and Zhong, {Rong Lin} and Takanori Miyazaki and Shigeyoshi Sakaki and Yoshiaki Nakao",

note = "Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

year = "2017",

month = jul,

day = "19",

doi = "10.1021/jacs.7b03159",

language = "English",

volume = "139",

pages = "9423--9426",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "28",

}

TY - JOUR

T1 - The Suzuki-Miyaura Coupling of Nitroarenes

AU - Yadav, M. Ramu

AU - Nagaoka, Masahiro

AU - Kashihara, Myuto

AU - Zhong, Rong Lin

AU - Miyazaki, Takanori

AU - Sakaki, Shigeyoshi

AU - Nakao, Yoshiaki

PY - 2017/7/19

Y1 - 2017/7/19

N2 - Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.

AB - Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.

UR - http://www.scopus.com/inward/record.url?scp=85024882614&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85024882614&partnerID=8YFLogxK

U2 - 10.1021/jacs.7b03159

DO - 10.1021/jacs.7b03159

M3 - Article

C2 - 28678486

AN - SCOPUS:85024882614

SN - 0002-7863

VL - 139

SP - 9423

EP - 9426

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 28

ER -

The Suzuki-Miyaura Coupling of Nitroarenes

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this