The Suzuki-Miyaura Coupling of Nitroarenes

M. Ramu Yadav, Masahiro Nagaoka, Myuto Kashihara, Rong Lin Zhong, Takanori Miyazaki, Shigeyoshi Sakaki, Yoshiaki Nakao

Research output: Contribution to journalArticlepeer-review

121 Citations (Scopus)

Abstract

Synthesis of biaryls via the Suzuki-Miyaura coupling (SMC) reaction using nitroarenes as an electrophilic coupling partners is described. Mechanistic studies have revealed that the catalytic cycle of this reaction is initiated by the cleavage of the aryl-nitro (Ar-NO2) bond by palladium, which represents an unprecedented elemental reaction.

Original languageEnglish
Pages (from-to)9423-9426
Number of pages4
JournalJournal of the American Chemical Society
Volume139
Issue number28
DOIs
Publication statusPublished - Jul 19 2017
Externally publishedYes

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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