The structural and magnetic properties in TDAE-fullerene system

Kokichi Oshima, Yoshio Nogami, Takashi Kambe, Nobuaki Nagao, Motoyasu Fujiwara

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

The structural and magnetic properties are discussed on the TDAE-fullerene system for C60 and C70. The single crystal structural analysis reveals that the TDAE-C70 system contains solvent molecules (toluene), and the C70 molecules in the unit cell are dimerized. The room temperature structure is monoclinic P21/n, and crystal parameters are a=18.82(3) Å, b=16.38(2) Å, c=18.73(3) Å and β=117.58(5)°. The same annealing procedure used in TDAE-C60 does not alter the magnetic behavior in TDAE-C70. A preliminary report is given for the TDAE-C60 structural study in magnetic fields up to 7 T. The possible method that directly reveals the relation between magnetism and the molecular arrangement is proposed.

Original languageEnglish
Title of host publicationNanonetwork Materials
Subtitle of host publicationFullerenes, Nanotubes, and Related Systems
EditorsTsuneya Ando, Yoshihiro Iwasawa, Koichi Kikuchi, Yahachi Saito, Susumu Saito, Mototada Kobayashi
PublisherAmerican Institute of Physics Inc.
Pages393-396
Number of pages4
ISBN (Electronic)0735400326, 9780735400320
DOIs
Publication statusPublished - Oct 16 2001
EventInternational Symposium on Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems 2001 - Kamakura, Japan
Duration: Jan 15 2001Jan 18 2001

Publication series

NameAIP Conference Proceedings
Volume590
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Other

OtherInternational Symposium on Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems 2001
CountryJapan
CityKamakura
Period1/15/011/18/01

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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  • Cite this

    Oshima, K., Nogami, Y., Kambe, T., Nagao, N., & Fujiwara, M. (2001). The structural and magnetic properties in TDAE-fullerene system. In T. Ando, Y. Iwasawa, K. Kikuchi, Y. Saito, S. Saito, & M. Kobayashi (Eds.), Nanonetwork Materials: Fullerenes, Nanotubes, and Related Systems (pp. 393-396). (AIP Conference Proceedings; Vol. 590). American Institute of Physics Inc.. https://doi.org/10.1063/1.1420135