The quality of SiC film formed by thermal reaction of C60 monolayer on Si(111)-(7×7) surface

Kazuyuki Sakamoto, Takanori Wakita, Toshinao Suzuki, Shozo Suto, Chang W. Hu, Atsuo Kasuya

Research output: Contribution to journalArticle

Abstract

We have investigated the quality of SiC film formed by the thermal reaction of C60 molecules on Si(111)-(7×7) surface by the combined measurements of high-resolution electron-energy-loss spectroscopy (HREELS) and scanning tunneling microscopy (STM), HREELS-STM. The surface phonon energy of SiC film, formed by heating the C60 monolayer adsorbed Si(111)-(7×7) surface up to 1173 K, is observed at 114 meV. Moreover, new peaks are measured at 91, 102, 192, 205, 215 and 228 meV in high resolution measurements. STM image of SiC films shows the presence of many domains which surface areas are 10×10-35 nm2. Taking into account of the areas of SiC islands, we attribute the electron energy loss peaks at 91, 102 and 114 meV to the Si-C bonding at the SiC surfaces, the low frequency Fuchs-Kliewer phonon mode and the high-frequency one, respectively. The electron energy loss peaks observed around 200 meV is estimated to be the combination bands of those at 91, 102 and 114 meV. Considering the redshift of Fuchs-Kliewer phonon, SiC film formed by the thermal reaction of Si substrate with 1 ML of C60 is mainly composed of the "buffer" layer. The coupling of modes perpendicular and parallel to the surface indicate that the SiC surface is not idealy flat.

Original languageEnglish
Pages (from-to)55-58
Number of pages4
JournalScience Reports of the Rerearch Institutes Tohoku University Series A-Physics
Volume44
Issue number1
Publication statusPublished - 1997
Externally publishedYes

Fingerprint

Monolayers
Scanning tunneling microscopy
energy dissipation
electron energy
scanning tunneling microscopy
Electron energy loss spectroscopy
high resolution
Energy dissipation
Electrons
Buffer layers
Hot Temperature
spectroscopy
buffers
low frequencies
Heating
Molecules
heating
Substrates
molecules

Keywords

  • C
  • Electron energy loss spectroscopy
  • Scanning tunneling microscopy
  • Silicon
  • Silicon carbide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Metals and Alloys

Cite this

The quality of SiC film formed by thermal reaction of C60 monolayer on Si(111)-(7×7) surface. / Sakamoto, Kazuyuki; Wakita, Takanori; Suzuki, Toshinao; Suto, Shozo; Hu, Chang W.; Kasuya, Atsuo.

In: Science Reports of the Rerearch Institutes Tohoku University Series A-Physics, Vol. 44, No. 1, 1997, p. 55-58.

Research output: Contribution to journalArticle

Sakamoto, Kazuyuki ; Wakita, Takanori ; Suzuki, Toshinao ; Suto, Shozo ; Hu, Chang W. ; Kasuya, Atsuo. / The quality of SiC film formed by thermal reaction of C60 monolayer on Si(111)-(7×7) surface. In: Science Reports of the Rerearch Institutes Tohoku University Series A-Physics. 1997 ; Vol. 44, No. 1. pp. 55-58.
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