The oxorhenium(VII)-catalyzed direct condensation of phosphoric acid with an alcohol

Akira Sakakura, Mikimoto Katsukawa, Kazuaki Ishihara

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

(Chemical Equation Presented) Come together ... over Re: Oxorhenium-(VII) complexes catalyze the direct condensation of phosphoric acid with an alcohol to selectively give the corresponding phosphoric acid monoester on a 2-100-mmol scale (see scheme). This method should be useful for the industrially important synthesis of phosphoric acid monoesters.

Original languageEnglish
Pages (from-to)1423-1426
Number of pages4
JournalAngewandte Chemie - International Edition
Volume46
Issue number9
DOIs
Publication statusPublished - Jun 27 2007
Externally publishedYes

Keywords

  • Alcohols
  • Green chemistry
  • Homogeneous catalysis
  • Phosphoric acid monoesters
  • Rhenium

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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