The first example for reactivity umpolung of diaryliodonium salts: Chromium(II)-mediated arylation of aldehydes

Da Wei Chen; Kazuhiko Takai; Masahito Ochiai

doi:10.1016/S0040-4039(97)10197-6

The first example for reactivity umpolung of diaryliodonium salts: Chromium(II)-mediated arylation of aldehydes

Da Wei Chen, Kazuhiko Takai, Masahito Ochiai

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Reported is the reactivity umpolung of diaryliodonium salts mediated by anhydrous chromium dichloride in the presence of a NiCl₂ catalyst, which involves generation of an arylchromium(III) species, followed by the nucleophilic addition to aldehydes yielding benzyl alcohols.

Original language	English
Pages (from-to)	8211-8214
Number of pages	4
Journal	Tetrahedron Letters
Volume	38
Issue number	47
DOIs	https://doi.org/10.1016/S0040-4039(97)10197-6
Publication status	Published - Nov 24 1997

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(97)10197-6

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abstract = "Reported is the reactivity umpolung of diaryliodonium salts mediated by anhydrous chromium dichloride in the presence of a NiCl2 catalyst, which involves generation of an arylchromium(III) species, followed by the nucleophilic addition to aldehydes yielding benzyl alcohols.",

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AB - Reported is the reactivity umpolung of diaryliodonium salts mediated by anhydrous chromium dichloride in the presence of a NiCl2 catalyst, which involves generation of an arylchromium(III) species, followed by the nucleophilic addition to aldehydes yielding benzyl alcohols.

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The first example for reactivity umpolung of diaryliodonium salts: Chromium(II)-mediated arylation of aldehydes

Abstract

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